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N′-tert-Butyl-N,N-dimethylformamidine_Molecular_structure_CAS_23314-06-9)
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N′-tert-Butyl-N,N-dimethylformamidine

Catalog No. 299065 Name Sigma Aldrich
CAS Number 23314-06-9 Website http://www.sigmaaldrich.com
M. F. C7H16N2 Telephone 1-800-521-8956
M. W. 128.21534 Fax
Purity 97% Email
Storage Chembase ID: 150452

SYNONYMS

Title
N′-叔丁基-N,N-二甲基甲脒
IUPAC name
N'-tert-butyl-N,N-dimethylmethanimidamide
IUPAC Traditional name
N'-tert-butyl-N,N-dimethylmethanimidamide

DATABASE IDS

MDL Number MFCD00010756
PubChem SID 24858010
CAS Number 23314-06-9

PROPERTIES

Linear Formula HC[=NC(CH3)3]N(CH3)2
Purity 97%
Boiling Point 137-140 °C(lit.)
Density 0.815 g/mL at 25 °C(lit.)
Flash Point 34 °C
Flash Point 93.2 °F
Refractive Index n20/D 1.445(lit.)
GHS Pictograms GHS02
GHS Pictograms GHS05
GHS Signal Word Danger
GHS Hazard statements H226-H314
European Hazard Symbols Corrosive Corrosive (C)
MSDS Link Download
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
GHS Precautionary statements P280-P305 + P351 + P338-P310
RID/ADR UN 2920 8/PG 2
Risk Statements 10-34
Safety Statements 16-26-27-36/37/39-45
Hazard Class 8
UN Number 2920
Packing Group 2
German water hazard class 3

DETAILS

Description (English)
Packaging
5, 25 g in glass bottle
Application
Enamidine intermediates derived from this reagent and carbonyl compounds may be converted into homologated secondary amines, aldehydes or ketones.1 Review of formamidines as precursors to α-amino carbanions.2
Description (简体中文)
包装
5, 25 g in glass bottle
Application
由这种试剂衍生的 enamidine 中间体和羰基化合物可转化成同系仲胺、醛或酮。1关于甲脒作为 α-氨基碳负离子前体的综述。2

REFERENCES