Tris(dibenzylideneacetone)dipalladium(0)-chloroform adduct

• Catalog No.: 366315
• CAS Number: 52522-40-4
• M. F.: C52H43Cl3O3Pd2
• M. W.: 1035.09502

SYNONYMS

• Title: 三(二亚苄基丙酮)二钯(0)-氯仿加合物
• IUPAC name: tris(1,5-diphenylpenta-1,4-dien-3-one) trichloromethane dipalladium
• IUPAC Traditional name: chloroform tris(dibenzylideneacetone) dipalladium
• Synonyms: Pd2(dba)3 · CHCl3; 三(二亚苄基丙酮)二钯-氯仿络合物; Dipalladium-tris(dibenzylideneacetone)chloroform complex

DATABASE IDS

• MDL Number: MFCD00075479
• PubChem SID: 24862642
• CAS Number: 52522-40-4

PROPERTIES

• Linear Formula: (C6H5CH=CHCOCH=CHC6H5)3Pd2 · CHCl3
• Melting Point: 131-135 °C(lit.)
• GHS Signal Word: Warning
• GHS Hazard statements: H302-H315-H351
• European Hazard Symbols: Harmful (Xn)
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves
• GHS Precautionary statements: P281
• Risk Statements: 22-38-40
• Safety Statements: 36/37
• German water hazard class: 3

DETAILS

Description (English)

Packaging
1 g in glass bottle
250 mg in glass bottle
Application
Application Guide for Palladium Catalyzed Cross-Coupling Reactions
Cyclization catalyst.Catalyst for [2+2+2] cycloaddtion of didehydrotriphenylenes to the corresponding extended triphenylenes. Catalyst for the carbonylation of b,b-imidoyl iodides to the corresponding imidate esters used, in turn, to prepare cyclic, quaternary amino acids.

Description (简体中文)

包装
1 g in glass bottle
250 mg in glass bottle
Application
Application Guide for Palladium Catalyzed Cross-Coupling Reactions
环化反应的催化剂。 作为催化剂用于二脱氢苯并菲类化合物的 [2+2+2] 环加成反应，生成相应的苯并菲衍生物。作为催化剂用于 β,β-亚胺酰碘的羰基化反应，生成相应的酰亚胺酯，后者又可用于制备环季氨基酸。