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5,5-Dimethyl-1,3,2-dioxaphosphorinan-2-one_Molecular_structure_CAS_4090-60-2)
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5,5-Dimethyl-1,3,2-dioxaphosphorinan-2-one

Catalog No. 541524 Name Sigma Aldrich
CAS Number 4090-60-2 Website http://www.sigmaaldrich.com
M. F. C5H11O3P Telephone 1-800-521-8956
M. W. 150.112801 Fax
Purity 96% Email
Storage Chembase ID: 150253

SYNONYMS

Title
5,5-二甲基-1,3,2-二氧磷杂环己烷-2-酮
IUPAC name
5,5-dimethyl-1,3,2λ5-dioxaphosphinan-2-one
IUPAC Traditional name
5,5-dimethyl-1,3,2λ5-dioxaphosphinan-2-one
Synonyms
Neopentylglycol hydrogen phosphite
2,2-Dimethylpropane-1,3-diol cyclic phosphonate
Cyclic 2,2-dimethyltrimethylene phosphonate
Neopentylene phosphite

DATABASE IDS

PubChem SID 24878543
CAS Number 4090-60-2
EC Number 223-832-8

PROPERTIES

Empirical Formula (Hill Notation) C5H11O3P
Purity 96%
Flash Point 109 °C
Flash Point 228.2 °F
Melting Point 51-56 °C(lit.)
GHS Pictograms GHS05
GHS Signal Word Danger
GHS Hazard statements H314
European Hazard Symbols Corrosive Corrosive (C)
MSDS Link Download
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
GHS Precautionary statements P280-P305 + P351 + P338-P310
RID/ADR UN 1759 8/PG 3
Risk Statements 34
Safety Statements 26-36/37/39-45
Hazard Class 8
UN Number 1759
Packing Group 3
German water hazard class 3

DETAILS

Description (English)
Packaging
5 g in glass bottle
Application
Reactant for:
• Palladium(I) catalyzed addition of P(O)-H bonds1
• Highly regioselective modified Pudovik addition reaction2
• Radical reactions mediated by manganese(III) acetate3
• Stable cyclic DEPMPO derivatives as mechanistic markers of stereoselective hydroxyl radical adduct formation in biological systems4
• Copper-catalyzed aerobic oxidative dehydrogenative coupling reactions5
• Bisphosphonates/phosphanamidates as anticancer agents6
Description (简体中文)
包装
5 g in glass bottle
Application
Reactant for:
• Palladium(I) catalyzed addition of P(O)-H bonds1
• Highly regioselective modified Pudovik addition reaction2
• Radical reactions mediated by manganese(III) acetate3
• Stable cyclic DEPMPO derivatives as mechanistic markers of stereoselective hydroxyl radical adduct formation in biological systems4
• Copper-catalyzed aerobic oxidative dehydrogenative coupling reactions5
• Bisphosphonates/phosphanamidates as anticancer agents6

REFERENCES