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Diphenyl phosphoryl azide_Molecular_structure_CAS_26386-88-9)
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Diphenyl phosphoryl azide

Catalog No. 178756 Name Sigma Aldrich
CAS Number 26386-88-9 Website http://www.sigmaaldrich.com
M. F. C12H10N3O3P Telephone 1-800-521-8956
M. W. 275.199861 Fax
Purity 97% Email
Storage Chembase ID: 80572

SYNONYMS

Title
叠氮磷酸二苯酯
IUPAC name
{[azido(phenoxy)phosphoryl]oxy}benzene
IUPAC Traditional name
diphenylphosphoryl azide
Synonyms
二苯基磷酰叠氮化物
Phosphoric acid diphenyl ester azide
DPPA

DATABASE IDS

CAS Number 26386-88-9
EC Number 247-644-0
MDL Number MFCD00001987
PubChem SID 24850766
Beilstein Number 2058967

PROPERTIES

Linear Formula (C6H5O)2P(O)N3
Purity 97%
Boiling Point 157 °C/0.17 mmHg(lit.)
Density 1.277 g/mL at 25 °C(lit.)
Flash Point 112 °C
Flash Point 233.6 °F
Refractive Index n20/D 1.551(lit.)
GHS Pictograms GHS06
GHS Signal Word Danger
GHS Hazard statements H301-H311-H315-H319-H331-H335
European Hazard Symbols Toxic Toxic (T)
MSDS Link Download
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
GHS Precautionary statements P261-P280-P301 + P310-P305 + P351 + P338-P311
RID/ADR UN 3278 6.1/PG 2
Risk Statements 23/24/25-36/37/38
Safety Statements 26-36/37/39-45
Storage Temperature 2-8°C
Hazard Class 6.1
UN Number 3278
Packing Group 2
German water hazard class 3

DETAILS

Description (English)
Packaging
5, 25, 100 g in glass bottle
Application
Hydroazidation Catalyst for Facile Preparation of OrganoazidesReagent for synthesis of oligosaccharides linked with carbamate and urea bonds utilizing modified Curtis rearrangement1
Description (简体中文)
包装
5, 25, 100 g in glass bottle
Application
Hydroazidation Catalyst for Facile Preparation of OrganoazidesReagent for synthesis of oligosaccharides linked with carbamate and urea bonds utilizing modified Curtis rearrangement1

REFERENCES