(Diacetoxyiodo)benzene

• Catalog No.: 178721
• CAS Number: 3240-34-4
• M. F.: C10H11IO4
• M. W.: 322.09641
• Purity: 98%

SYNONYMS

• Title: 碘苯二乙酸
• IUPAC name: (acetyloxy)(phenyl)-λ^3-iodanyl acetate
• IUPAC Traditional name: phenyliodosodiacetate
• Synonyms: Iodosobenzene I,I-diacetate; 碘苯二乙酸酯; Iodobenzene I,I-diacetate; 二乙酸亚碘酰苯

DATABASE IDS

• CAS Number: 3240-34-4
• EC Number: 221-808-1
• MDL Number: MFCD00008692
• Beilstein Number: 1879369
• PubChem SID: 24850764

PROPERTIES

• Linear Formula: C6H5I(O2CCH3)2
• Purity: 98%
• Melting Point: 161-163 °C(lit.)
• Personal Protective Equipment: Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
• RTECS: DA3525000
• German water hazard class: 3

DETAILS

Description (English)

Application
Stoichiometric oxidant in the TEMPO oxidation of nerol to neral.1 Oxidant employed in the rhodium-catalyzed aziridination of olefins with sulfamate esters.2
Unactivated sp3 C-H bonds of both oxime and pyridine substrates undergo highly regio- and chemoselective Pd(II)-catalyzed oxygenation with PhI(OAc)2 as a stoichiometric oxidant.
Used in the room temperature Pd-catalyzed 2-arylation of indoles
Useful reagent for the synthesis of a wide variety of heterocyclic compounds.
Rh2(esp)2: An Exceptionally Efficient and Selective Catalyst for C-H Amination
Packaging
1 kg in glass bottle
5, 25, 100 g in glass bottle

Description (简体中文)

Application
Unactivated sp3 C-H bonds of both oxime and pyridine substrates undergo highly regio- and chemoselective Pd(II)-catalyzed oxygenation with PhI(OAc)2 as a stoichiometric oxidant.
橙花醇转化为橙花醛的 TEMPO 氧化反应中的化学计量氧化剂。1用作铑催化的烯烃与氨基磺酸酯进行氮杂环丙化反应中的氧化剂。2
用于合成各种杂环化合物的试剂。
用于室温下钯催化的吲哚的 2-芳基化反应。
Rh2(esp)2: An Exceptionally Efficient and Selective Catalyst for C-H Amination
包装
1 kg in glass bottle
5, 25, 100 g in glass bottle