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Triethyl 2-phosphonopropionate_Molecular_structure_CAS_3699-66-9)
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Triethyl 2-phosphonopropionate

Catalog No. 174653 Name Sigma Aldrich
CAS Number 3699-66-9 Website http://www.sigmaaldrich.com
M. F. C9H19O5P Telephone 1-800-521-8956
M. W. 238.217921 Fax
Purity 98% Email
Storage Chembase ID: 91243

SYNONYMS

Title
2-膦酰丙酸三乙酯
IUPAC name
ethyl 2-(diethoxyphosphoryl)propanoate
IUPAC Traditional name
ethyl 2-(diethoxyphosphoryl)propanoate
Synonyms
2-(Diethoxyphosphoryl)propionic acid ethyl ester

DATABASE IDS

Beilstein Number 1786994
MDL Number MFCD00009159
EC Number 223-033-4
CAS Number 3699-66-9
PubChem SID 24850353

PROPERTIES

Linear Formula (C2H5O)2P(O)CH(CH3)CO2C2H5
Purity 98%
Boiling Point 143-144 °C/12 mmHg(lit.)
Density 1.111 g/mL at 25 °C(lit.)
Flash Point 89 °C
Flash Point 192.2 °F
Refractive Index n20/D 1.431(lit.)
MSDS Link Download
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
German water hazard class 3

DETAILS

Description (English)
Packaging
10, 50 g in glass bottle
Application
Reactant involved in:
• Intramolecular conjugate addition for the synthesis of floresolide B1
• Chemoenzymatic one-pot synthesis of γ-butyrolactones2
• Enantioselective synthesis of spiroindane di-Me acetic acid via asymmetric hydrogenation3
• Stereoselective intramolecular Diels-Alder reactions4,5
• Horner-Wadsworth-Emmons reactions6
This Wittig-Horner reagent condenses with a wide variety of aldehydes and ketones to form acrylates.
Description (简体中文)
包装
10, 50 g in glass bottle
Application
Reactant involved in:
• Intramolecular conjugate addition for the synthesis of floresolide B1
• Chemoenzymatic one-pot synthesis of γ-butyrolactones2
• Enantioselective synthesis of spiroindane di-Me acetic acid via asymmetric hydrogenation3
• Stereoselective intramolecular Diels-Alder reactions4,5
• Horner-Wadsworth-Emmons reactions6
该 Wittig-Horner 试剂可与各种醛和酮发生缩合反应形成丙烯酸酯。

REFERENCES