Tris(triphenylphosphine)rhodium(I) chloride

• Catalog No.: 205036
• CAS Number: 14694-95-2
• M. F.: C54H45ClP3Rh
• M. W.: 925.214883
• Purity: 99.9% trace metals basis

SYNONYMS

• Title: 三(三苯基膦)氯化铑(I)
• IUPAC name: chlororhodium; tris(triphenylphosphane)
• IUPAC Traditional name: chlororhodium; tris(triphenylphosphine)
• Synonyms: Wilkinson 催化剂; RhCl(PPh3)3; Wilkinson’s catalyst; NSC 124140; Rhodium(I) tris(triphenylphosphine) chloride; 三(三苯膦基)氯化铑(I)

DATABASE IDS

• Beilstein Number: 4581440
• MDL Number: MFCD00010016
• PubChem SID: 24852305
• EC Number: 238-744-5
• CAS Number: 14694-95-2

PROPERTIES

• Linear Formula: [(C6H5)3P]3RhCl
• Purity: 99.9% trace metals basis
• Personal Protective Equipment: Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
• German water hazard class: 3

DETAILS

Description (English)

Application
Useful catalyst for the efficient cross-coupling of activated alkenyl tosylates with arylboronic acids.6 Also used to catalyze the cleavage of allyl phenolic ethers to phenols with DABCO.7
Hydrosilylation CatalystsCatalyst used for many organic reactions including:
• Chemoselective allylic alkylations1
• Stoichiometric activation of Si-H bonds2 and hydrosilylations3
• Inter- and intramolecular hydroacylation of alkenes along with a cocatalyst4
• Polymerization of diorganostannanes5
Packaging
1 g in glass bottle
250 mg in glass bottle
5 g in poly bottle

Description (简体中文)

Application
用于芳基硼酸与活化的烯基甲苯磺酸酯进行交叉偶联反应的有效催化剂。6也用于催化 DABCO 作用下烯丙基酚醚裂解为酚。7
Hydrosilylation CatalystsCatalyst used for many organic reactions including:
• Chemoselective allylic alkylations1
• Stoichiometric activation of Si-H bonds2 and hydrosilylations3
• Inter- and intramolecular hydroacylation of alkenes along with a cocatalyst4
• Polymerization of diorganostannanes5
包装
1 g in glass bottle
250 mg in glass bottle
5 g in poly bottle