Ethynylmagnesium bromide solution

• Catalog No.: 346152
• CAS Number: 4301-14-8
• M. F.: C2HBrMg
• M. W.: 129.23834

SYNONYMS

• Title: 乙炔基溴化镁 溶液
• IUPAC name: bromo(ethynyl)magnesium
• IUPAC Traditional name: bromo(ethynyl)magnesium

DATABASE IDS

• CAS Number: 4301-14-8
• MDL Number: MFCD00075342
• Beilstein Number: 3600874
• PubChem SID: 24861376

PROPERTIES

• Concentration: 0.5 M in THF
• Linear Formula: HC≡CMgBr
• Density: 0.94 g/mL at 25 °C
• Flash Point: -29 °C
• Flash Point: -20.2 °F
• GHS Signal Word: Danger
• GHS Hazard statements: H225-H261-H314-H335
• European Hazard Symbols: Flammable (F)
• European Hazard Symbols: Corrosive (C)
• Personal Protective Equipment: Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
• GHS Precautionary statements: P210-P231 + P232-P261-P280-P305 + P351 + P338-P422
• RID/ADR: UN 3399 4.3/PG 2
• Risk Statements: 11-14/15-19-34-37
• Safety Statements: 9-16-26-36/37/39-43-45
• Storage Temperature: 2-8°C
• Supplemental Hazard Statements: May form explosive peroxides., Reacts violently with water.
• Hazard Class: 4.3
• UN Number: 3399
• Packing Group: 2
• German water hazard class: 3

DETAILS

Description (English)

Application
Preparation of the alkyne component in an enyne cross-metathesis leading to conjugated dienes.1 Diastereoselective ethynylation of chiral α-(dibenzylamino) aldehydes.2
Packaging
100, 800 mL in Sure/Seal™

Description (简体中文)

Application
在形成共轭二烯的烯炔交叉复分解反应中制备炔烃组分。1手性 α-(联苄氨基)醛的非对映选择性乙炔化。2
包装
100, 800 mL in Sure/Seal™