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(2S)-(+)-Glycidyl tosylate_Molecular_structure_CAS_70987-78-9)
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(2S)-(+)-Glycidyl tosylate

Catalog No. 540129 Name Sigma Aldrich
CAS Number 70987-78-9 Website http://www.sigmaaldrich.com
M. F. C10H12O4S Telephone 1-800-521-8956
M. W. 228.26488 Fax
Purity 98% Email
Storage Chembase ID: 74255

SYNONYMS

Title
(2S)-(+)-缩水甘油对甲苯磺酸酯
IUPAC name
(2S)-oxiran-2-ylmethyl 4-methylbenzene-1-sulfonate
IUPAC Traditional name
(2S)-oxiran-2-ylmethyl 4-methylbenzenesulfonate
Synonyms
(S)-(+)-Glycidyl p-toluenesulfonate
(S)-(+)-环氧乙烷-2-甲醇对甲苯磺酸酯
(S)-(+)-对甲苯磺酸缩水甘油酯
(S)-(+)-Oxirane-2-methanol p-toluenesulfonate

DATABASE IDS

MDL Number MFCD00064489
Beilstein Number 3592143
CAS Number 70987-78-9
EC Number 417-210-7
PubChem SID 24878443

PROPERTIES

Empirical Formula (Hill Notation) C10H12O4S
Purity 98%
Flash Point 113 °C
Flash Point 235.4 °F
Melting Point 46-49 °C(lit.)
GHS Pictograms GHS05
GHS Pictograms GHS07
GHS Pictograms GHS08
GHS Pictograms GHS09
GHS Signal Word Danger
GHS Hazard statements H317-H318-H341-H350-H411
European Hazard Symbols Toxic Toxic (T)
European Hazard Symbols Nature polluting Nature polluting (N)
MSDS Link Download
GHS Precautionary statements P201-P273-P280-P305 + P351 + P338-P308 + P313
RID/ADR UN 3077 9/PG 3
Risk Statements 45-41-43-51/53-68
RTECS RR0510050
Safety Statements 53-45-61
Storage Temperature 2-8°C
Hazard Class 9
UN Number 3077
Packing Group 3
German water hazard class 3
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges

DETAILS

Description (English)
Application
Used in the first enantioselective synthesis of (R)- and (S)-4-acetyl-3-(hydroxymethyl)-3,4-dihydro-2H-pyrido[3,2-b]oxazines.1
Packaging
5, 25 g in glass bottle
Legal Information
Manufactured under license by Shasun Chemicals and Drugs Limited, using Jacobsen HKR technology.
Description (简体中文)
Application
用于第一不对称合成 (R)- 和 (S)-4-乙酰基-3-(羟甲基)-3,4-二氢-2H-吡啶并[3,2-b]噁嗪。1
包装
5, 25 g in glass bottle
Legal Information
经 Shasun Chemicals and Drugs Limited 授权,使用 Jacobsen HKR 技术制造。

REFERENCES