Potassium triethylborohydride solution

• Catalog No.: 213438
• CAS Number: 22560-21-0
• M. F.: C6H15BK
• M. W.: 137.0926

SYNONYMS

• Title: 三乙基氢硼化钾 溶液
• IUPAC name: potassium triethylboranuide
• IUPAC Traditional name: potassium lithium triethylborohydride
• Synonyms: Potassium hydrotriethylborate; Potassium triethylhydridoborate

DATABASE IDS

• MDL Number: MFCD00011702
• PubChem SID: 24852782
• CAS Number: 22560-21-0

PROPERTIES

• Concentration: 1.0 M in THF
• Linear Formula: KB(C2H5)3H
• Density: 0.902 g/mL at 25 °C
• Flash Point: -17 °C
• Flash Point: 1.4 °F
• GHS Signal Word: Danger
• GHS Hazard statements: H225-H260-H314-H335
• European Hazard Symbols: Flammable (F)
• European Hazard Symbols: Corrosive (C)
• GHS Precautionary statements: P210-P223-P231 + P232-P261-P370 + P378-P422
• RID/ADR: UN 3399 4.3/PG 1
• Risk Statements: 11-14/15-19-34-37
• Safety Statements: 16-26-36/37/39-43-45
• Supplemental Hazard Statements: May form explosive peroxides., Reacts violently with water.
• Hazard Class: 4.3
• UN Number: 3399
• Packing Group: 1
• German water hazard class: 3

DETAILS

Description (English)

Packaging
100 mL in Sure/Seal™
Application

• Reducing agent for synthesis of PtNi intermetallic nanoparticle catalysts with electrocatalytic activity1
• Reducing agent for preparation of vanadium nanoparticles (~7 nm) stabilized on activated carbon2Reagent for:
• Preparation of lithium, sodium, and potassium boron monohydride complexes with tetramethylethylenediamine and pentamethyldiethylenetriamine3
• Dehydrogenation reactions4
• Tandem nucleophilic addition/C-C bond cleaving fragmentation reactions with cyclic vinylogous acyl triflates5
• Preparation of coordinatively unsaturated pseudotetrahedral iron(II) precursors as precatalysts for the room-temperature hydrogenation of unsaturated hydrocarbons6
• Substitution reactions7

Description (简体中文)

包装
100 mL in Sure/Seal™
Application

• Reducing agent for synthesis of PtNi intermetallic nanoparticle catalysts with electrocatalytic activity1
• Reducing agent for preparation of vanadium nanoparticles (~7 nm) stabilized on activated carbon2Reagent for:
• Preparation of lithium, sodium, and potassium boron monohydride complexes with tetramethylethylenediamine and pentamethyldiethylenetriamine3
• Dehydrogenation reactions4
• Tandem nucleophilic addition/C-C bond cleaving fragmentation reactions with cyclic vinylogous acyl triflates5
• Preparation of coordinatively unsaturated pseudotetrahedral iron(II) precursors as precatalysts for the room-temperature hydrogenation of unsaturated hydrocarbons6
• Substitution reactions7