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Di-tert-butylsilyl bis(trifluoromethanesulfonate)_Molecular_structure_CAS_85272-31-7)
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Di-tert-butylsilyl bis(trifluoromethanesulfonate)

Catalog No. 262021 Name Sigma Aldrich
CAS Number 85272-31-7 Website http://www.sigmaaldrich.com
M. F. C10H18F6O6S2Si Telephone 1-800-521-8956
M. W. 440.4522392 Fax
Purity 97% Email
Storage Chembase ID: 98060

SYNONYMS

Title
二叔丁基硅基双(三氟甲烷磺酸)
IUPAC name
di-tert-butyl(trifluoromethanesulfonyloxy)silyl trifluoromethanesulfonate
IUPAC Traditional name
di-tert-butyl(trifluoromethanesulfonyloxy)silyl trifluoromethanesulfonate
Synonyms
二叔丁基硅基双(三氟甲烷磺酸)酯
DTBS 二(三氟甲磺酸酯)
DTBS ditriflate
Di-tert-butylsilyl ditriflate
Trifluoromethanesulfonic acid di-tert-butylsilylene ester
二叔丁基双(三氟甲磺酰氧基)硅烷

DATABASE IDS

Beilstein Number 3569211
CAS Number 85272-31-7
MDL Number MFCD00010581
PubChem SID 24855853

PROPERTIES

Linear Formula (CF3SO3)2Si[C(CH3)3]2
Purity 97%
Boiling Point 73-75 °C/0.35 mmHg(lit.)
Density 1.352 g/mL at 25 °C(lit.)
Flash Point 91 °C
Flash Point 195.8 °F
Refractive Index n20/D 1.398(lit.)
GHS Pictograms GHS05
GHS Signal Word Danger
GHS Hazard statements H314
European Hazard Symbols Corrosive Corrosive (C)
MSDS Link Download
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
GHS Precautionary statements P280-P305 + P351 + P338-P310
RID/ADR UN 3265 8/PG 2
Risk Statements 34
Safety Statements 26-36/37/39-45
Hazard Class 8
UN Number 3265
Packing Group 2
German water hazard class 3

DETAILS

Description (English)
Application
Protecting group reagent for 1,3-diols used recently in a synthesis of N-homoceramides.1 Also used for selective α-galactosylation in the synthesis of α-galactosyl ceramides.2
Packaging
5, 25 g in glass bottle
Description (简体中文)
Application
1,3-二醇的保护基团试剂,近年来用于 N-人神经酰胺合成。1也用于在 α-半乳糖神经酰胺合成过程中的选择性 α-半乳糖基化。2
包装
5, 25 g in glass bottle

REFERENCES