4-Bromophenylboronic acid

• Catalog No.: B75956
• CAS Number: 5467-74-3
• M. F.: C6H6BBrO2
• M. W.: 200.82564
• Purity: ≥95.0%

SYNONYMS

• Title: 4-溴苯硼酸
• IUPAC name: (4-bromophenyl)boronic acid
• IUPAC Traditional name: 4-bromophenylboric acid
• Synonyms: (p-Bromophenyl)boronic acid; p-Bromophenylboric acid; NSC 25407; 4-Bromophenylboric acid; p-Bromobenzeneboronic acid; 4-Bromobenzeneboronic acid; 4-溴苯基硼酸

DATABASE IDS

• PubChem SID: 24892010
• Beilstein Number: 2936347
• EC Number: 226-779-9
• CAS Number: 5467-74-3
• MDL Number: MFCD00002104

PROPERTIES

• Linear Formula: BrC6H4B(OH)2
• Purity: ≥95.0%
• Purity: 95%
• Melting Point: 284-288 °C(lit.)
• GHS Signal Word: Warning
• GHS Hazard statements: H315-H319-H335
• European Hazard Symbols: Irritant (Xi)
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves
• GHS Precautionary statements: P261-P305 + P351 + P338
• Risk Statements: 36/37/38
• RTECS: CY8650000
• Safety Statements: 26
• German water hazard class: 3

DETAILS

Description (简体中文)

Other Notes
含不定量的酸酐
包装
1, 5 g in glass bottle
Application
Reagent used for
• Palladium catalyzed Suzuki-Miyaura cross-couplings1
• Pd(II)-catalyzed diastereoselective conjugate additions2
• Palladium-catalyzed stereoselective Heck-type reaction of allylic esters with arylboronic acids3
• Tandem-type Pd(II)-catalyzed oxidative Heck reaction and intramolecular C-H amidation sequence4
• Copper-mediated ligandless aerobic fluoroalkylation of arylboronic acids with fluoroalkyl iodides5
• Pd-catalyzed arylative cyclization of alkyne-tethered enals or enones via carbopalladation of alkynes6
• Copper-catalyzed cross-couplings7,8Reagent used in Preparation of
• Gallate-based obovatol analogs with potential anti-tumor activity9
• Protein modulators and enzymatic and kinase inhibitors10,11

Description (English)

Other Notes
Contains varying amounts of anhydride
Packaging
1, 5 g in glass bottle
Application
Reagent used for
• Palladium catalyzed Suzuki-Miyaura cross-couplings1
• Pd(II)-catalyzed diastereoselective conjugate additions2
• Palladium-catalyzed stereoselective Heck-type reaction of allylic esters with arylboronic acids3
• Tandem-type Pd(II)-catalyzed oxidative Heck reaction and intramolecular C-H amidation sequence4
• Copper-mediated ligandless aerobic fluoroalkylation of arylboronic acids with fluoroalkyl iodides5
• Pd-catalyzed arylative cyclization of alkyne-tethered enals or enones via carbopalladation of alkynes6
• Copper-catalyzed cross-couplings7,8Reagent used in Preparation of
• Gallate-based obovatol analogs with potential anti-tumor activity9
• Protein modulators and enzymatic and kinase inhibitors10,11