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(2R)-(-)-Glycidyl tosylate_Molecular_structure_CAS_113826-06-5)
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(2R)-(-)-Glycidyl tosylate

Catalog No. 540110 Name Sigma Aldrich
CAS Number 113826-06-5 Website http://www.sigmaaldrich.com
M. F. C10H12O4S Telephone 1-800-521-8956
M. W. 228.26488 Fax
Purity 98% Email
Storage Chembase ID: 70128

SYNONYMS

Title
(2R)-(-)-对甲苯磺酸缩水甘油酯
IUPAC name
(2R)-oxiran-2-ylmethyl 4-methylbenzene-1-sulfonate
IUPAC Traditional name
(2R)-oxiran-2-ylmethyl 4-methylbenzenesulfonate
Synonyms
(R)-(-)-Glycidyl tosylate
(R)-(-)-Oxirane-2-methanol p-toluenesulfonate salt
(R)-(-)-Glycidyl p-toluenesulfonate
(R)-(-)-环氧乙烷-2-甲醇 对甲苯磺酸盐
(R)-(-)-缩水甘油基对甲苯磺酸酯
(R)-(-)-缩水甘油基甲苯磺酸酯

DATABASE IDS

Beilstein Number 3592142
MDL Number MFCD00010834
PubChem SID 24878442
CAS Number 113826-06-5

PROPERTIES

Empirical Formula (Hill Notation) C10H12O4S
Purity 98%
Flash Point 113 °C
Flash Point 235.4 °F
Melting Point 46-49 °C(lit.)
GHS Pictograms GHS05
GHS Pictograms GHS08
GHS Signal Word Danger
GHS Hazard statements H318-H334-H350
European Hazard Symbols Toxic Toxic (T)
European Hazard Symbols Nature polluting Nature polluting (N)
MSDS Link Download
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
GHS Precautionary statements P201-P261-P280-P305 + P351 + P338-P308 + P313
RID/ADR UN 3077 9/PG 3
Risk Statements 45-41-43-51/53-68
RTECS RR0510000
Safety Statements 53-26-36/37/39-45-61
Storage Temperature 2-8°C
Hazard Class 9
UN Number 3077
Packing Group 3
German water hazard class 3

DETAILS

Description (English)
Application
Used in the first enantioselective synthesis of (R)- and (S)-4-acetyl-3-(hydroxymethyl)-3,4-dihydro-2H-pyrido[3,2-b]oxazines.1
Packaging
5, 25 g in glass bottle
Legal Information
Manufactured under license by Shasun Chemicals and Drugs Limited, using Jacobsen HKR technology.
Description (简体中文)
Application
用于第一不对称合成 (R)- 和 (S)-4-乙酰基-3-(羟甲基)-3,4-二氢-2H-吡啶并[3,2-b]噁嗪。1
包装
5, 25 g in glass bottle
Legal Information
经 Shasun Chemicals and Drugs Limited 授权,使用 Jacobsen HKR 技术制造。

REFERENCES