Dichloro[rac-ethylenebis(4,5,6,7-tetrahydro-1-indenyl)]zirconium(IV)

• Catalog No.: 532126
• CAS Number: 100163-29-9
• M. F.: C20H24Cl2Zr
• M. W.: 426.53456
• Purity: 97%

SYNONYMS

• Title: [rac-乙烯双(4,5,6,7-四氢-1-茚基)]二氯化锆(IV)
• IUPAC name: 1-[2-(4,5,6,7-tetrahydro-2H-inden-2-id-1-yl)ethyl]-4,5,6,7-tetrahydro-2H-inden-2-ide; dichlorozirconiumbis(ylium)
• IUPAC Traditional name: 1-[2-(4,5,6,7-tetrahydro-2H-inden-2-id-1-yl)ethyl]-4,5,6,7-tetrahydro-2H-inden-2-ide; dichlorozirconiumbis(ylium)
• Synonyms: Dichloro[rel-(7aR,7′aR)-1,2-ethanediylbis[(1,2,3,3a,7a-η)-4,5,6,7-tetrahydro-1H-inden-1-ylidene]]zirconium

DATABASE IDS

• PubChem SID: 24877859
• MDL Number: MFCD00672123
• CAS Number: 100163-29-9

PROPERTIES

• Empirical Formula (Hill Notation): C20H24Cl2Zr
• Purity: 97%
• Melting Point: 267-271 °C(lit.)
• GHS Signal Word: Warning
• GHS Hazard statements: H315-H319-H335
• European Hazard Symbols: Irritant (Xi)
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves
• GHS Precautionary statements: P261-P305 + P351 + P338
• Risk Statements: 36/37/38
• Safety Statements: 26-36
• German water hazard class: 3

DETAILS

Description (English)

Packaging
500 mg in glass bottle
Application
Catalyst for:
• Regiochemistry in Negishi carboaluminations1
• Polymerization of olefins2
• Diastereoselective intramolecular olefin alkylations3
• Asymmetric carbomagnesiation4
• Reduction of esters to alcohols5
• Enantioselective synthesis of allylic amines6

Description (简体中文)

包装
500 mg in glass bottle
Application
Catalyst for:
• Regiochemistry in Negishi carboaluminations1
• Polymerization of olefins2
• Diastereoselective intramolecular olefin alkylations3
• Asymmetric carbomagnesiation4
• Reduction of esters to alcohols5
• Enantioselective synthesis of allylic amines6