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(S)-(+)-2-(Methoxymethyl)pyrrolidine_Molecular_structure_CAS_63126-47-6)
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(S)-(+)-2-(Methoxymethyl)pyrrolidine

Catalog No. 277053 Name Sigma Aldrich
CAS Number 63126-47-6 Website http://www.sigmaaldrich.com
M. F. C6H13NO Telephone 1-800-521-8956
M. W. 115.17352 Fax
Purity 99% Email
Storage Chembase ID: 149379

SYNONYMS

Title
(S)-(+)-2-(甲氧基甲基)吡咯烷
IUPAC name
(2S)-2-(methoxymethyl)pyrrolidine
IUPAC Traditional name
(2S)-2-(methoxymethyl)pyrrolidine
Synonyms
O-甲基-L-脯氨醇
O-Methyl-L-prolinol
SMP

DATABASE IDS

Beilstein Number 3587324
PubChem SID 24856730
CAS Number 63126-47-6
MDL Number MFCD00010408

PROPERTIES

Empirical Formula (Hill Notation) C6H13NO
Purity 99%
Boiling Point 62 °C/40 mmHg(lit.)
Density 0.933 g/mL at 25 °C(lit.)
Flash Point 45 °C
Flash Point 113 °F
Optical Rotation [α]20/D +2.4°, c = 2 in benzene
Refractive Index n20/D 1.4457(lit.)
GHS Pictograms GHS02
GHS Pictograms GHS07
GHS Signal Word Warning
GHS Hazard statements H226-H315-H319-H335
European Hazard Symbols Irritant Irritant (Xi)
MSDS Link Download
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
GHS Precautionary statements P261-P305 + P351 + P338
RID/ADR UN 1993 3/PG 3
Risk Statements 10-36/37/38
Safety Statements 26-36
Hazard Class 3
UN Number 1993
Packing Group 3
German water hazard class 3

DETAILS

Description (English)
Packaging
5 g in glass bottle
500 mg in glass bottle
Application
Chiral auxiliary for asymmetric synthesis of propargyl alcohols1 and 4-nitrocyclohexanones,2 and for asymmetric Michael additions to enones.3
Description (简体中文)
包装
5 g in glass bottle
500 mg in glass bottle
Application
手性助剂,用于不对称合成炔丙醇1 和 4-硝基环己酮,2 以及用于不对称 Michael 加成反应生成烯酮。3

REFERENCES