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(S)-4-Benzyl-2-oxazolidinone_Molecular_structure_CAS_90719-32-7)
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(S)-4-Benzyl-2-oxazolidinone

Catalog No. 294640 Name Sigma Aldrich
CAS Number 90719-32-7 Website http://www.sigmaaldrich.com
M. F. C10H11NO2 Telephone 1-800-521-8956
M. W. 177.19984 Fax
Purity 99% Email
Storage Chembase ID: 149354

SYNONYMS

Title
(S)-4-苄基-2-噁唑烷酮
IUPAC name
(4S)-4-benzyl-1,3-oxazolidin-2-one
IUPAC Traditional name
(4S)-4-benzyl-1,3-oxazolidin-2-one

DATABASE IDS

PubChem SID 24857725
MDL Number MFCD00064496
CAS Number 90719-32-7
Beilstein Number 3649667

PROPERTIES

Empirical Formula (Hill Notation) C10H11NO2
Optical Purity ee: 99% (HPLC)
Purity 99%
Melting Point 86-88 °C(lit.)
Optical Rotation [α]20/D -63°, c = 1 in chloroform
MSDS Link Download
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
German water hazard class 3

DETAILS

Description (English)
Application
Chiral auxiliary for asymmetric alkylation.
Chiral auxiliary used recently in a synthesis of (S)-equol. Preparation and functionalization of chiral, stabilized ylides.
Used for asymmetric synthesis of (3R)- and (3S)-piperazic acid.1
Packaging
25 g in poly bottle
5 g in glass bottle
Description (简体中文)
Application
手性助剂,最近用于合成 (S)-雌马酚。用于制备和官能化稳定的手性叶立德。
用于不对称合成 (3R)- 和 (3S)-六氢哒嗪-3-羧酸。1
用于不对称烷化反应的手性助剂。
包装
25 g in poly bottle
5 g in glass bottle

REFERENCES