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tert-Butyldimethylsilyl chloride_Molecular_structure_CAS_18162-48-6)
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tert-Butyldimethylsilyl chloride

Catalog No. 190500 Name Sigma Aldrich
CAS Number 18162-48-6 Website http://www.sigmaaldrich.com
M. F. C6H15ClSi Telephone 1-800-521-8956
M. W. 150.7218 Fax
Purity 97% Email
Storage Chembase ID: 73799

SYNONYMS

Title
叔丁基二甲基硅基氯
IUPAC name
tert-butyl(chloro)dimethylsilane
IUPAC Traditional name
t-butyldimethylchlorosilane
Synonyms
tert-Butyldimethylchlorosilane
叔丁基(氯)二甲基硅烷
TBDMSCl
tert-Butyl(chloro)dimethylsilane
叔丁基二甲基氯硅烷

DATABASE IDS

EC Number 242-042-4
CAS Number 18162-48-6
MDL Number MFCD00000501
Beilstein Number 505999
PubChem SID 24851442

PROPERTIES

Grade reagent grade
Linear Formula (CH3)3CSi(CH3)2Cl
Purity 97%
Boiling Point 125 °C(lit.)
Flash Point 22 °C
Flash Point 71.6 °F
Melting Point 86-89 °C(lit.)
GHS Pictograms GHS02
GHS Pictograms GHS05
GHS Signal Word Danger
GHS Hazard statements H228-H314
European Hazard Symbols Corrosive Corrosive (C)
MSDS Link Download
GHS Precautionary statements P210-P280-P305 + P351 + P338-P310
RID/ADR UN 2925 4.1/PG 2
Risk Statements 10-34
RTECS VV2000000
Safety Statements 16-26-36/37/39-45
Hazard Class 4.1
UN Number 2925
Packing Group 2
German water hazard class 2

DETAILS

Description (English)
Frequently Asked Questions
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Packaging
1 kg in glass bottle
5, 25, 100, 500 g in glass bottle
Application
Versatile protecting reagent for amines, amides, and especially alcohols, among others.1 Can be selectively removed in the presence of a t-BuPh2Si-protected alcohol.2Used in a preparatrion of isoxazoline N-oxides from α-bromonitroalkanes.3
Description (简体中文)
Frequently Asked Questions
Live Chat and Frequently Asked Questions are available for this Product.
包装
1 kg in glass bottle
5, 25, 100, 500 g in glass bottle
Application
胺、酰胺,尤其是醇的多功能保护试剂。1在 t-BuPh2Si 保护醇存在的条件下,可被选择性除去。2 用于由 α-溴硝基烷制备异噁唑啉 N-氧化物。3

REFERENCES