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Silver trifluoromethanesulfonate

Catalog No. 176435 Name Sigma Aldrich
CAS Number 2923-28-6 Website http://www.sigmaaldrich.com
M. F. CAgF3O3S Telephone 1-800-521-8956
M. W. 256.9373096 Fax
Purity ≥99% Email
Storage Chembase ID: 8488

SYNONYMS

Title
三氟甲烷磺酸银
IUPAC name
silver(1+) ion trifluoromethanesulfonate
IUPAC Traditional name
silver(1+) ion triflate
Synonyms
Silver triflate
三氟甲磺酸银
三氟甲磺酸 银盐
Trifluoromethanesulfonic acid silver salt

DATABASE IDS

CAS Number 2923-28-6
MDL Number MFCD00013226
EC Number 220-882-2
PubChem SID 24850578
Beilstein Number 3598402

PROPERTIES

Linear Formula CF3SO3Ag
Purity ≥99%
Melting Point 286 °C(lit.)
GHS Pictograms GHS07
GHS Signal Word Warning
GHS Hazard statements H315-H319-H335
European Hazard Symbols Irritant Irritant (Xi)
MSDS Link Download
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
GHS Precautionary statements P261-P305 + P351 + P338
Risk Statements 36/37/38
Safety Statements 26-36
German water hazard class 3

DETAILS

Description (English)
Packaging
1, 10, 25 g in glass bottle
Application
Gold Catalysts - 21st Century ′Gold Rush′
Yields olefins from secondary phosphates and thiophosphates. Using this reagent the etherification of alcohols with primary alkyl halides can be accomplished under mild conditions.Used to generate cationic rhodium catalysts from chlororhodium complexes for the hydrophosphination of acetylenes. Also employed as a catalyst for the preparation of silyl ethers by hydrosilylation of aldehydes.
Description (简体中文)
包装
1, 10, 25 g in glass bottle
Application
Gold Catalysts - 21st Century ′Gold Rush′
由仲磷酸盐和硫代磷酸盐生成烯烃。使用该试剂,伯烷基卤化物对醇的醚化可以在温和条件下实现。 用于由氯铑络合物生成阳离子铑催化剂,以用于乙炔的氢化亚膦酸化。还用作通过醛的氢化硅烷化来制备硅醚的催化剂。

REFERENCES