1-Z-4-Piperidone

• Catalog No.: 464643
• CAS Number: 19099-93-5
• M. F.: C13H15NO3
• M. W.: 233.2631
• Purity: 99%

SYNONYMS

• Title: 1-Cbz-4-哌啶酮
• IUPAC name: benzyl 4-oxopiperidine-1-carboxylate
• IUPAC Traditional name: benzyl 4-oxopiperidine-1-carboxylate
• Synonyms: 1-(Benzyloxycarbonyl)-4-piperidinone; Benzyl 4-oxo-1-piperidinecarboxylate; 1-苄氧羰基-4-哌啶酮; 1-Cbz-4-Piperidone; N-CBZ-4-哌啶酮; N-苄氧羰基-4-哌啶酮

DATABASE IDS

• CAS Number: 19099-93-5
• PubChem SID: 24870202
• MDL Number: MFCD00673144
• Beilstein Number: 1533716

PROPERTIES

• Empirical Formula (Hill Notation): C13H15NO3
• Purity: 99%
• Boiling Point: 114-140 °C/0.25 mmHg(lit.)
• Density: 1.172 g/mL at 25 °C(lit.)
• Flash Point: 113 °C
• Flash Point: 235.4 °F
• Refractive Index: n20/D 1.542(lit.)
• Personal Protective Equipment: Eyeshields, Gloves, half-mask respirator (US), multi-purpose combination respirator cartridge (US)
• German water hazard class: 3

DETAILS

Description (English)

Application
Protected piperidinone that can undergo interesting synthetic transformations including the Knoevenagel reaction,1 hetero-Diels-Alder reactions,2 and reactions to form N-(4-piperidinyl)oxindoles.3
Starting material in a synthesis of a GABA analogue by direct Barbier-like addition of an alkyl phosphinate.
Packaging
5, 25, 100 mL in glass bottle

Description (简体中文)

Application
保护性哌啶酮，可进行倍受关注的合成转化反应，包括 Knoevenagel 反应、1非均相 Diels-Alder 反应2以及生成 N-(4-哌啶基)羟基吲哚的反应。3
通过烷基次膦酸盐的直接 Barbier-型加成反应合成 GABA 类似物时的原料。
包装
5, 25, 100 mL in glass bottle