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1H-Benzotriazole-1-methanol

Catalog No. 410233 Name Sigma Aldrich
CAS Number 28539-02-8 Website http://www.sigmaaldrich.com
M. F. C7H7N3O Telephone 1-800-521-8956
M. W. 149.14998 Fax
Purity 98% Email
Storage Chembase ID: 87158

SYNONYMS

Title
1H-苯并三唑-1-甲醇
IUPAC name
1H-1,2,3-benzotriazol-1-ylmethanol
IUPAC Traditional name
1,2,3-benzotriazol-1-ylmethanol
Synonyms
1-(Hydroxymethyl)benzotriazole
1-Benzotriazolemethanol
NSC 12463

DATABASE IDS

PubChem SID 24865702
MDL Number MFCD00179118
CAS Number 28539-02-8

PROPERTIES

Empirical Formula (Hill Notation) C7H7N3O
Purity 98%
Melting Point 150-152 °C(lit.)
GHS Pictograms GHS07
GHS Signal Word Warning
GHS Hazard statements H315-H319-H335
European Hazard Symbols Irritant Irritant (Xi)
MSDS Link Download
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
GHS Precautionary statements P261-P305 + P351 + P338
Risk Statements 36/37/38
Safety Statements 26-36
German water hazard class 3

DETAILS

Description (English)
Application
Safe reagent for the in situ generation of anhydrous formaldehyde in organic solvents.8
Catalyst for:
• Hydrolysis of phenyl esters of a-furoic acid1Used as:
• Corrosion inhibitor of iron in aerated acidic media2
• Reactive oxygen scavenger3Reactant for:
• Synthesis of hydroxy-skipped bis-homo-inositols as potential glycosidase inhibitors via Sharpless asymmetric dihydroxylation and substrate-directed anionic hydroxymethylation4
• Enantioselective synthesis of aplysin utilizing a palladium-catalyzed addition of an arylboronic acid to an allenic alcohol, followed by Eschenmoser/Claisen rearrangement5
• Synthesis of substituted dihydroquinoline carboxylic acids as antitumor and HIV-1 integrase inhibitors6
• Gosteli-Claisen rearrangement7
Packaging
10, 50 g in glass bottle
Description (简体中文)
Application
用于在有机溶剂中原位合成无水甲醛的安全剂。8
Catalyst for:
• Hydrolysis of phenyl esters of a-furoic acid1Used as:
• Corrosion inhibitor of iron in aerated acidic media2
• Reactive oxygen scavenger3Reactant for:
• Synthesis of hydroxy-skipped bis-homo-inositols as potential glycosidase inhibitors via Sharpless asymmetric dihydroxylation and substrate-directed anionic hydroxymethylation4
• Enantioselective synthesis of aplysin utilizing a palladium-catalyzed addition of an arylboronic acid to an allenic alcohol, followed by Eschenmoser/Claisen rearrangement5
• Synthesis of substituted dihydroquinoline carboxylic acids as antitumor and HIV-1 integrase inhibitors6
• Gosteli-Claisen rearrangement7
包装
10, 50 g in glass bottle

REFERENCES