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tert-Butylmagnesium chloride solution_Molecular_structure_CAS_677-22-5)
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tert-Butylmagnesium chloride solution

Catalog No. 224499 Name Sigma Aldrich
CAS Number 677-22-5 Website http://www.sigmaaldrich.com
M. F. C4H9ClMg Telephone 1-800-521-8956
M. W. 116.87226 Fax
Purity Email
Storage Chembase ID: 137261

SYNONYMS

Title
叔丁基氯化镁 溶液
IUPAC name
tert-butyl(chloro)magnesium
IUPAC Traditional name
tert-butyl(chloro)magnesium

DATABASE IDS

MDL Number MFCD00000465
Beilstein Number 3535403
PubChem SID 24853442
CAS Number 677-22-5

PROPERTIES

Concentration 2.0 M in diethyl ether
Linear Formula (CH3)3CMgCl
Density 0.828 g/mL at 25 °C
Flash Point -40 °C
Flash Point -40 °F
GHS Pictograms GHS02
GHS Pictograms GHS05
GHS Pictograms GHS07
GHS Signal Word Danger
GHS Hazard statements H225-H261-H302-H314-H336
European Hazard Symbols Flammable Flammable (F)
European Hazard Symbols Corrosive Corrosive (C)
MSDS Link Download
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
GHS Precautionary statements P210-P231 + P232-P261-P280-P305 + P351 + P338-P422
RID/ADR UN 3399 4.3/PG 1
Risk Statements 11-14/15-19-22-34-67
Safety Statements 16-26-36/37/39-45
Supplemental Hazard Statements May form explosive peroxides., Reacts violently with water.
Hazard Class 4.3
UN Number 3399
Packing Group 1
German water hazard class 3

DETAILS

Description (English)
Application
Reagent used in an Fe(acac)3-catalyzed cross-coupling with chloroenynols.1
Packaging
100, 800 mL in Sure/Seal™
Description (简体中文)
Application
用于 Fe(acac)3 催化的与 chloroenynols 的交叉偶联反应。1
包装
100, 800 mL in Sure/Seal™

REFERENCES