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Di-tert-butylchlorophosphine_Molecular_structure_CAS_13716-10-4)
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Di-tert-butylchlorophosphine

Catalog No. 301558 Name Sigma Aldrich
CAS Number 13716-10-4 Website http://www.sigmaaldrich.com
M. F. C8H18ClP Telephone 1-800-521-8956
M. W. 180.655281 Fax
Purity 96% Email
Storage Chembase ID: 148992

SYNONYMS

Title
二叔丁基氯化膦
IUPAC name
di-tert-butyl(chloro)phosphane
IUPAC Traditional name
di-tert-butyl(chloro)phosphane

DATABASE IDS

PubChem SID 24858196
MDL Number MFCD00008815
CAS Number 13716-10-4

PROPERTIES

Linear Formula [(CH3)3C]2PCl
Purity 96%
Boiling Point 48 °C/3 mmHg(lit.)
Density 0.951 g/mL at 25 °C(lit.)
Flash Point 62 °C
Flash Point 143.6 °F
Ligand For Suzuki-Miyaura Coupling
Refractive Index n20/D 1.482(lit.)
GHS Pictograms GHS05
GHS Signal Word Danger
GHS Hazard statements H314
European Hazard Symbols Corrosive Corrosive (C)
MSDS Link Download
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
GHS Precautionary statements P280-P305 + P351 + P338-P310
RID/ADR UN 3265 8/PG 2
Risk Statements 34
Safety Statements 26-36/37/39-45
Hazard Class 8
UN Number 3265
Packing Group 2
German water hazard class 3

DETAILS

Description (English)
Application
Bulky ligand used with Pd(OAc)2 in efficient Suzuki-Miyaura cross-couplings of arylboronic acids with aryl bromides and chlorides.1
Packaging
1, 5 g in glass bottle
25, 100 g in Sure/Seal™
Description (简体中文)
Application
与 Pd(OAc)2 配合使用的大体积配体,用于芳基硼酸和溴代芳烃及氯代芳烃之间的高效 Suzuki-Miyaura 交叉偶联反应。1
包装
1, 5 g in glass bottle
25, 100 g in Sure/Seal™

REFERENCES