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Diisobutylaluminum hydride solution_Molecular_structure_CAS_1191-15-7)
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Diisobutylaluminum hydride solution

Catalog No. 214949 Name Sigma Aldrich
CAS Number 1191-15-7 Website http://www.sigmaaldrich.com
M. F. C8H19Al Telephone 1-800-521-8956
M. W. 142.217998 Fax
Purity Email
Storage Chembase ID: 127050

SYNONYMS

Title
二异丁基氢化铝 溶液
IUPAC name
bis(2-methylpropyl)alumane
IUPAC Traditional name
diisobutylaluminium hydride
Synonyms
DIBAL-H
DIBAL

DATABASE IDS

CAS Number 1191-15-7
MDL Number MFCD00008928
Beilstein Number 4123663
PubChem SID 24852856

PROPERTIES

Concentration 1.0 M in cyclohexane
Linear Formula [(CH3)2CHCH2]2AlH
Density 0.781 g/mL at 25 °C
Flash Point -17 °C
Flash Point 1.4 °F
GHS Pictograms GHS02
GHS Pictograms GHS05
GHS Pictograms GHS07
GHS Pictograms GHS08
GHS Pictograms GHS09
GHS Signal Word Danger
GHS Hazard statements H225-H250-H261-H304-H314-H336-H410
European Hazard Symbols Flammable Flammable (F)
European Hazard Symbols Corrosive Corrosive (C)
European Hazard Symbols Nature polluting Nature polluting (N)
MSDS Link Download
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
GHS Precautionary statements P210-P222-P231 + P232-P261-P273-P422
RID/ADR UN 3399 4.3/PG 1
Risk Statements 11-14/15-17-34-50/53-65-67
Safety Statements 26-36/37/39-43-45-61-62
Hazard Class 4.3
UN Number 3399
Packing Group 1
German water hazard class 3

DETAILS

Description (English)
Application
Used in Pd-catalyzed reductive debromination of secondary alkyl bromides.1 O-Debenzylation and ring opening of perbenzylated furanosides.2 Convenient in situ generation of HZrCp2Cl from ZrCp2Cl2 and DIBAL-H.3
Packaging
100, 800 mL in Sure/Seal™
Description (简体中文)
Application
Used in Pd-catalyzed reductive debromination of secondary alkyl bromides.1 O-Debenzylation and ring opening of perbenzylated furanosides.2 Convenient in situ generation of HZrCp2Cl from ZrCp2Cl2 and DIBAL-H.3
包装
100, 800 mL in Sure/Seal™

REFERENCES