4-Ethynylanisole

• Catalog No.: 206490
• CAS Number: 768-60-5
• M. F.: C9H8O
• M. W.: 132.15922
• Purity: 97%

SYNONYMS

• Title: 4-乙炔基苯甲醚
• IUPAC name: 1-ethynyl-4-methoxybenzene
• IUPAC Traditional name: 1-ethynyl-4-methoxybenzene
• Synonyms: 1-乙炔-4-甲氧基苯; 1-Ethynyl-4-methoxybenzene

DATABASE IDS

• PubChem SID: 24852402
• MDL Number: MFCD00168815
• CAS Number: 768-60-5

PROPERTIES

• Linear Formula: CH3OC6H4C≡CH
• Purity: 97%
• Boiling Point: 87-91 °C/11 mmHg(lit.)
• Density: 1.019 g/mL at 25 °C(lit.)
• Flash Point: 82 °C
• Flash Point: 179.6 °F
• Melting Point: 28-29 °C(lit.)
• Refractive Index: n20/D 1.563(lit.)
• Personal Protective Equipment: Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
• German water hazard class: 3

DETAILS

Description (English)

Application
1,3-dipolar cycloaddition of acceptor-cyclopropylmethylsilanes affords functionalized cyclopentenes in good yields.1
Forms the corresponding propargyl aldehyde in good yield directly from DMF-dimethyl acetal without the need for making an acetylide salt.
Used together with an arylboronic acid and sodium azide in a copper-catalyzed, three-component synthesis of trisubstituted 1,2,4-triazoles. Employed in a study of a gold (III)-catalyzed hydroamination of alkynes leading to N-vinylindoles.
Packaging
1, 5 g in glass bottle

Description (简体中文)

Application
与芳基硼酸和叠氮化钠一起，用于三取代 1,2,4-三唑类化合物的铜催化、三组分合成。用于研究金 (III) 催化的炔烃氢胺化反应，形成 N-乙烯基吲哚。
无需制备乙炔化物盐，直接由 N,N-二甲基甲酰胺二甲基缩醛以高产率形成对应的丙炔醛。
进行受体-环丙基甲硅烷的 1,3-偶极环加成反应，以高收率得到官能化的环戊烯类化合物。1
包装
1, 5 g in glass bottle