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N-tert-Butyldimethylsilyl-N-methyltrifluoroacetamide with 1% tert-Butyldimethylchlorosilane_Molecular_structure_CAS_77377-52-7)
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N-tert-Butyldimethylsilyl-N-methyltrifluoroacetamide with 1% tert-Butyldimethylchlorosilane

Catalog No. 375934 Name Sigma Aldrich
CAS Number 77377-52-7 Website http://www.sigmaaldrich.com
M. F. C9H18F3NOSi Telephone 1-800-521-8956
M. W. 241.3260296 Fax
Purity ≥95% Email
Storage Chembase ID: 8559

SYNONYMS

Title
N-叔丁基二甲基甲硅烷基-N-甲基三氟乙酰胺,含 1% 叔丁基二甲基氯硅烷
IUPAC name
N-(tert-butyldimethylsilyl)-2,2,2-trifluoro-N-methylacetamide
IUPAC Traditional name
N-(tert-butyldimethylsilyl)-2,2,2-trifluoro-N-methylacetamide
Synonyms
Silylating mixture Fluka VI
N-Methyl-N-tert-butyldimethylsilyltrifluoroacetamide
MTBSTFA + 1% TBDMSCl
MTBSTFA+TBDMSCl, 99:1
N-甲基-N-叔丁基二甲基甲硅烷基三氟乙酰胺
甲硅烷基化混合物 Fluka VI

DATABASE IDS

MDL Number MFCD00009671
PubChem SID 24863412
CAS Number 77377-52-7
Beilstein Number 3606546

PROPERTIES

Contains 1% TBDMSCl
Empirical Formula (Hill Notation) C9H18F3NOSi
Purity ≥95%
Flash Point 45 °C
Flash Point 113 °F
GHS Pictograms GHS02
GHS Pictograms GHS05
GHS Pictograms GHS07
GHS Signal Word Danger
GHS Hazard statements H226-H314-H335
European Hazard Symbols Irritant Irritant (Xi)
MSDS Link Download
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
GHS Precautionary statements P261-P280-P305 + P351 + P338-P310
RID/ADR UN 1993 3/PG 3
Risk Statements 10-36/37/38
Safety Statements 26
Storage Temperature -20°C
Hazard Class 3
UN Number 1993
Packing Group 3
German water hazard class 3

DETAILS

Description (English)
Application
Preparation of N-tert-butyldimethylsilyl ethanolamines resulting from hydrolysis of nitrogen mustards.
Selective O-silylation of N,O-diacylhydroxylamines.1
Packaging
10×1 mL in ampule
5, 25 mL in glass bottle
Description (简体中文)
Application
用于 N,O-二酰基羟胺的选择性 O-甲硅烷基化。1
用于氮芥的水解反应制备 N-叔丁基二甲基甲硅烷基乙醇胺。
包装
10×1 mL in ampule
5, 25 mL in glass bottle

REFERENCES