Europium tris[3-(trifluoromethylhydroxymethylene)-(+)-camphorate]

• Catalog No.: 176494
• CAS Number: 34830-11-0
• M. F.: C36H42EuF9O6
• M. W.: 893.6647088

SYNONYMS

• Title: 三[3-(三氟甲基羟亚甲基)-(+)-樟脑酸]铕
• IUPAC name: tris(2,2,2-trifluoro-1-{4,7,7-trimethyl-3-oxobicyclo[2.2.1]heptan-2-ylidene}ethoxy)europium
• IUPAC Traditional name: tris(2,2,2-trifluoro-1-{4,7,7-trimethyl-3-oxobicyclo[2.2.1]heptan-2-ylidene}ethoxy)europium
• Synonyms: 三[3-(三氟甲基羟亚甲基))-d-樟脑酸]铕(III); Tris[3-(trifluoromethylhydroxymethylene)-d-camphorato]europium(III); 三(3-三氟乙酰基-d-樟脑)合铕(III); 三[3-(三氟甲基羟亚甲基)-d-樟脑]合铕(III); Eu(tfc)3; Eu(facam)3; Europium(III) tris[3-(trifluoromethylhydroxymethylene)-d-camphorate]; Tris(3-trifluoroacetyl-d-camphorato)europium(III)

DATABASE IDS

• MDL Number: MFCD00074803
• PubChem SID: 24850581
• CAS Number: 34830-11-0
• EC Number: 252-232-9

PROPERTIES

• Empirical Formula (Hill Notation): C36H42EuF9O6
• Optical Rotation: [α]20/D +165°, c = 1% in chloroform (solvent is ethanol free)
• Personal Protective Equipment: Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
• German water hazard class: 3

DETAILS

Description (English)

Application
Optically active NMR shift reagent. Used with Ag(fod) for the enantiomeric resolution of sec-butylisothiouronium chloride.3
Reactant involved in:
• The synthesis of europium acetylcamphorate phosphine oxide complexes1
• Reactions with 1,10-N,N′-phenanthroline dioxide derivatives2
Packaging
1 g in glass bottle
100 mg in glass bottle

Description (简体中文)

Application
具有光学活性的 NMR 位移试剂。与 Ag(fod) 一起用于仲丁基氯化异硫脲的对映体拆分。3
Reactant involved in:
• The synthesis of europium acetylcamphorate phosphine oxide complexes1
• Reactions with 1,10-N,N′-phenanthroline dioxide derivatives2
包装
1 g in glass bottle
100 mg in glass bottle