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Europium tris[3-(trifluoromethylhydroxymethylene)-(+)-camphorate]_Molecular_structure_CAS_34830-11-0)
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Europium tris[3-(trifluoromethylhydroxymethylene)-(+)-camphorate]

Catalog No. 176494 Name Sigma Aldrich
CAS Number 34830-11-0 Website http://www.sigmaaldrich.com
M. F. C36H42EuF9O6 Telephone 1-800-521-8956
M. W. 893.6647088 Fax
Purity Email
Storage Chembase ID: 138941

SYNONYMS

Title
三[3-(三氟甲基羟亚甲基)-(+)-樟脑酸]铕
IUPAC name
tris(2,2,2-trifluoro-1-{4,7,7-trimethyl-3-oxobicyclo[2.2.1]heptan-2-ylidene}ethoxy)europium
IUPAC Traditional name
tris(2,2,2-trifluoro-1-{4,7,7-trimethyl-3-oxobicyclo[2.2.1]heptan-2-ylidene}ethoxy)europium
Synonyms
三[3-(三氟甲基羟亚甲基))-d-樟脑酸]铕(III)
Tris[3-(trifluoromethylhydroxymethylene)-d-camphorato]europium(III)
三(3-三氟乙酰基-d-樟脑)合铕(III)
三[3-(三氟甲基羟亚甲基)-d-樟脑]合铕(III)
Eu(tfc)3
Eu(facam)3
Europium(III) tris[3-(trifluoromethylhydroxymethylene)-d-camphorate]
Tris(3-trifluoroacetyl-d-camphorato)europium(III)

DATABASE IDS

MDL Number MFCD00074803
PubChem SID 24850581
CAS Number 34830-11-0
EC Number 252-232-9

PROPERTIES

Empirical Formula (Hill Notation) C36H42EuF9O6
Optical Rotation [α]20/D +165°, c = 1% in chloroform (solvent is ethanol free)
MSDS Link Download
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
German water hazard class 3

DETAILS

Description (English)
Application
Optically active NMR shift reagent. Used with Ag(fod) for the enantiomeric resolution of sec-butylisothiouronium chloride.3
Reactant involved in:
• The synthesis of europium acetylcamphorate phosphine oxide complexes1
• Reactions with 1,10-N,N′-phenanthroline dioxide derivatives2
Packaging
1 g in glass bottle
100 mg in glass bottle
Description (简体中文)
Application
具有光学活性的 NMR 位移试剂。与 Ag(fod) 一起用于仲丁基氯化异硫脲的对映体拆分。3
Reactant involved in:
• The synthesis of europium acetylcamphorate phosphine oxide complexes1
• Reactions with 1,10-N,N′-phenanthroline dioxide derivatives2
包装
1 g in glass bottle
100 mg in glass bottle

REFERENCES