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Dess-Martin periodinane_Molecular_structure_CAS_87413-09-0)
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Dess-Martin periodinane

Catalog No. 274623 Name Sigma Aldrich
CAS Number 87413-09-0 Website http://www.sigmaaldrich.com
M. F. C13H13IO8 Telephone 1-800-521-8956
M. W. 424.14199 Fax
Purity 97% Email
Storage Chembase ID: 70652

SYNONYMS

Title
戴斯-马丁氧化剂
IUPAC name
1,1-bis(acetyloxy)-3-oxo-3H-1λ5,2-benziodaoxol-1-yl acetate
IUPAC Traditional name
dess-martin periodinane
Synonyms
1,1,1-三(乙酰氧基)-1,1-二氢-1,2-苯碘酰-3-(1H)-酮
1,1,1-Tris(acetyloxy)-1,1-dihydro-1,2-benziodoxol-3-(1H)-one

DATABASE IDS

MDL Number MFCD00130127
CAS Number 87413-09-0
PubChem SID 24856593

PROPERTIES

Empirical Formula (Hill Notation) C13H13IO8
Purity 97%
Melting Point 130-133 °C(lit.)
GHS Pictograms GHS03
GHS Pictograms GHS07
GHS Signal Word Warning
GHS Hazard statements H272-H302-H312-H315-H319-H332-H335
European Hazard Symbols Oxidising Oxidising (O)
European Hazard Symbols Harmful Harmful (Xn)
MSDS Link Download
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
GHS Precautionary statements P220-P261-P280-P305 + P351 + P338
Risk Statements 8-20/21/22-36/37/38-44
Safety Statements 26-36
Storage Temperature -20°C
Supplemental Hazard Statements Risk of explosion if heated under confinement.
German water hazard class 3

DETAILS

Description (English)
Application
Oxidizing agent for 1° and 2° alcohols to aldehydes and ketones.1,2
Used for the oxidation of hydroxychlorins to chlorin-α-diones and tetraones.
Packaging
1, 5, 25, 50, 250 g in glass bottle
Description (简体中文)
Application
用于将 1° 和 2° 醇氧化为醛和酮的氧化剂。1,2
用于将羟基二氢卟酚氧化为二氢卟酚-α-二酮和四酮。
包装
1, 5, 25, 50, 250 g in glass bottle

REFERENCES