Tributyltin hydride

• Catalog No.: 234788
• CAS Number: 688-73-3
• M. F.: C12H27Sn
• M. W.: 290.04378
• Purity: 97%

SYNONYMS

• Title: 三丁基氢化锡
• IUPAC name: tributylstannane
• IUPAC Traditional name: tributyltin

DATABASE IDS

• Beilstein Number: 3587329
• PubChem SID: 24854056
• CAS Number: 688-73-3
• MDL Number: MFCD00009416

PROPERTIES

• Contains: 0.05% BHT as stabilizer
• Linear Formula: [CH3(CH2)3]3SnH
• Purity: 97%
• Boiling Point: 80 °C/0.4 mmHg(lit.)
• Density: 1.082 g/mL at 25 °C(lit.)
• Flash Point: 40 °C
• Flash Point: 104 °F
• Refractive Index: n20/D 1.473(lit.)
• GHS Signal Word: Danger
• GHS Hazard statements: H226-H301-H312-H315-H319-H372-H410
• European Hazard Symbols: Toxic (T)
• European Hazard Symbols: Nature polluting (N)
• Personal Protective Equipment: Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
• GHS Precautionary statements: P273-P280-P301 + P310-P305 + P351 + P338-P314-P501
• RID/ADR: UN 1993 3/PG 3
• Risk Statements: 10-21-25-36/38-48/23/25-50/53
• Safety Statements: 26-36/37-45-61
• Storage Temperature: 2-8°C
• Hazard Class: 3
• UN Number: 1993
• Packing Group: 3
• German water hazard class: 3

DETAILS

Description (English)

Application
A widely used radical reagent used in reductive cleavage,1 radical dehalogenation, and intramolecular radical cyclization.2
Radical promoted intramolecular cyclization leading to isoxazolo-benzaulene ring system. Vinyl tin fragment used in a synthesis of (+)-panepophenanthrin via biomimetic Diels-Alder dimerization.
Packaging
10 g in glass bottle
50, 500 g in Sure/Seal™

Description (简体中文)

Application
广泛使用的自由基试剂，可用于还原裂解、1自由基脱卤以及分子内自由基环化。2
自由基促进的分子内环化反应可生成 isoxazolo-benzaulene 环系。乙烯基锡片段可用于通过仿生 Diels-Alder 二聚化反应合成 (+)-panepophenanthrin
包装
10 g in glass bottle
50, 500 g in Sure/Seal™