Diisobutylaluminum hydride solution

• Catalog No.: 214981
• CAS Number: 1191-15-7
• M. F.: C8H19Al
• M. W.: 142.217998

SYNONYMS

• Title: 二异丁基氢化铝 溶液
• IUPAC name: bis(2-methylpropyl)alumane
• IUPAC Traditional name: diisobutylaluminium hydride
• Synonyms: DIBAL-H; DIBAL

DATABASE IDS

• PubChem SID: 24852859
• CAS Number: 1191-15-7
• MDL Number: MFCD00008928
• Beilstein Number: 4123663

PROPERTIES

• Concentration: 1.0 M in THF
• Linear Formula: [(CH3)2CHCH2]2AlH
• Boiling Point: 65 °C
• Density: 0.866 g/mL at 25 °C
• Flash Point: -17 °C
• Flash Point: 1.4 °F
• GHS Signal Word: Danger
• GHS Hazard statements: H225-H250-H260-H314-H335
• European Hazard Symbols: Flammable (F)
• European Hazard Symbols: Corrosive (C)
• Personal Protective Equipment: Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US)
• GHS Precautionary statements: P210-P222-P223-P231 + P232-P370 + P378-P422
• RID/ADR: UN 3399 4.3/PG 1
• Risk Statements: 11-14/15-17-19-34-37
• Safety Statements: 16-26-36/37/39-43-45
• Storage Temperature: 2-8°C
• Supplemental Hazard Statements: May form explosive peroxides.
• Hazard Class: 4.3
• UN Number: 3399
• Packing Group: 1
• German water hazard class: 1

DETAILS

Description (English)

Application
Used in Pd-catalyzed reductive debromination of secondary alkyl bromides.1 O-Debenzylation and ring opening of perbenzylated furanosides.2 Convenient in situ generation of HZrCp2Cl from ZrCp2Cl2 and DIBAL-H.3
Packaging
100, 800 mL in Sure/Seal™
18 L in Kilo-Lab™
View returnable container options.

Description (简体中文)

Application
Used in Pd-catalyzed reductive debromination of secondary alkyl bromides.1 O-Debenzylation and ring opening of perbenzylated furanosides.2 Convenient in situ generation of HZrCp2Cl from ZrCp2Cl2 and DIBAL-H.3
包装
100, 800 mL in Sure/Seal™
18 L in Kilo-Lab™
View returnable container options.