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Methyl trifluoromethanesulfonate_Molecular_structure_CAS_333-27-7)
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Methyl trifluoromethanesulfonate

Catalog No. 164283 Name Sigma Aldrich
CAS Number 333-27-7 Website http://www.sigmaaldrich.com
M. F. C2H3F3O3S Telephone 1-800-521-8956
M. W. 164.1036296 Fax
Purity ≥98% Email
Storage Chembase ID: 8489

SYNONYMS

Title
三氟甲磺酸甲酯
IUPAC name
methyl trifluoromethanesulfonate
IUPAC Traditional name
triflate ester
Synonyms
Methyl triflate
三氟甲基磺酸甲酯

DATABASE IDS

Beilstein Number 774772
EC Number 206-371-7
MDL Number MFCD00000409
CAS Number 333-27-7
PubChem SID 24850067

PROPERTIES

Linear Formula CF3SO2OCH3
Purity ≥98%
Boiling Point 94-99 °C(lit.)
Density 1.45 g/mL at 25 °C(lit.)
Flash Point 38 °C
Flash Point 100.4 °F
Refractive Index n20/D 1.326(lit.)
GHS Pictograms GHS02
GHS Pictograms GHS05
GHS Signal Word Danger
GHS Hazard statements H226-H314
European Hazard Symbols Corrosive Corrosive (C)
MSDS Link Download
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
GHS Precautionary statements P280-P305 + P351 + P338-P310
RID/ADR UN 2920 8/PG 2
Risk Statements 10-34
Safety Statements 26-36/37/39-45
Storage Temperature 2-8°C
Hazard Class 8
UN Number 2920
Packing Group 2
German water hazard class 3

DETAILS

Description (English)
Application
Shown to be the most effective monomethylating agent in reactions with potassium enolates.1
Useful methylation reagent for the conversion of amines to methyl ammonium triflates.
Packaging
10, 50 g in ampule
Description (简体中文)
Application
在烯醇化钾的反应中是最有效的单甲基化剂。1
有效的甲基化试剂,用于将胺转化为甲基三氟甲基磺酸铵。
包装
10, 50 g in ampule

REFERENCES