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(Trimethylsilyl)methyllithium solution_Molecular_structure_CAS_1822-00-0)
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(Trimethylsilyl)methyllithium solution

Catalog No. 297054 Name Sigma Aldrich
CAS Number 1822-00-0 Website http://www.sigmaaldrich.com
M. F. C4H11LiSi Telephone 1-800-521-8956
M. W. 94.15664 Fax
Purity Email
Storage Chembase ID: 148378

SYNONYMS

Title
三甲基硅甲基锂 溶液
IUPAC name
(lithiomethyl)trimethylsilane
IUPAC Traditional name
(lithiomethyl)trimethylsilane

DATABASE IDS

PubChem SID 24857896
MDL Number MFCD00010747
Beilstein Number 4123225
CAS Number 1822-00-0

PROPERTIES

Concentration 1.0 M in pentane
Linear Formula (CH3)3SiCH2Li
Boiling Point 35-36 °C
Density 0.65 g/mL at 25 °C
Flash Point -49 °C
Flash Point -56.2 °F
GHS Pictograms GHS02
GHS Pictograms GHS05
GHS Pictograms GHS07
GHS Pictograms GHS08
GHS Pictograms GHS09
GHS Signal Word Danger
GHS Hazard statements H224-H304-H314-H336-H411
European Hazard Symbols Flammable Flammable (F)
European Hazard Symbols Corrosive Corrosive (C)
European Hazard Symbols Nature polluting Nature polluting (N)
MSDS Link Download
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US)
GHS Precautionary statements P210-P261-P273-P280-P301 + P310-P305 + P351 + P338
RID/ADR UN 3399 4.3/PG 1
Risk Statements 11-14-34-51/53-65-67
Safety Statements 16-26-36/37/39-45-61-62
Storage Temperature 2-8°C
Supplemental Hazard Statements Reacts violently with water.
Hazard Class 4.3
UN Number 3399
Packing Group 1
German water hazard class 3

DETAILS

Description (English)
Packaging
4×25, 50, 600 mL in Sure/Seal™
Application
Initiates polymerization and copolymerization of cyclosiloxanes.1 Alkylates metal complexes.2
Description (简体中文)
包装
4×25, 50, 600 mL in Sure/Seal™
Application
启动环硅氧烷的聚合和共聚合反应。1金属络合物的烷基化反应。2

REFERENCES