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4-Methoxybenzyl chloride_Molecular_structure_CAS_824-94-2)
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4-Methoxybenzyl chloride

Catalog No. 270245 Name Sigma Aldrich
CAS Number 824-94-2 Website http://www.sigmaaldrich.com
M. F. C8H9ClO Telephone 1-800-521-8956
M. W. 156.60946 Fax
Purity 98% Email
Storage Chembase ID: 82999

SYNONYMS

Title
4-甲氧基氯苄
IUPAC name
1-(chloromethyl)-4-methoxybenzene
IUPAC Traditional name
4-methoxybenzyl chloride
Synonyms
4-(Chloromethyl)anisole
4-(氯甲基)苯甲醚

DATABASE IDS

Beilstein Number 606667
PubChem SID 24856365
MDL Number MFCD00000915
EC Number 212-540-6
CAS Number 824-94-2

PROPERTIES

Contains potassium carbonate as stabilizer
Linear Formula CH3OC6H4CH2Cl
Purity 98%
Boiling Point 117-118 °C/14 mmHg(lit.)
Density 1.155 g/mL at 25 °C(lit.)
Flash Point 109 °C
Flash Point 228.2 °F
Melting Point -1 °C(lit.)
Refractive Index n20/D 1.548(lit.)
GHS Pictograms GHS05
GHS Signal Word Danger
GHS Hazard statements H314
European Hazard Symbols Corrosive Corrosive (C)
MSDS Link Download
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
GHS Precautionary statements P280-P305 + P351 + P338-P310
RID/ADR UN 3265 8/PG 3
Risk Statements 34
Safety Statements 26-27-36/37/39-45
Storage Temperature 2-8°C
Hazard Class 8
UN Number 3265
Packing Group 3
German water hazard class 3

DETAILS

Description (English)
Application
Employed in a synthesis of diarymethanes via Suzuki cross-coupling with postassium aryltrifluoroborates.1
O/N protecting group reagent which can be mildly oxidatively cleaved, e.g., with ceric ammonium nitrate.
Packaging
5, 25 g in glass bottle
Description (简体中文)
Application
O/N 保护基团试剂,可以发生温和地氧化裂解,例如使用硝酸铈铵。
用于与芳基三氟硼酸钾发生 Suzuki 交叉偶联反应合成二芳基甲烷。1
包装
5, 25 g in glass bottle

REFERENCES