AD-mix-α

• Catalog No.: 392758
• M. F.: C48H54N6O4
• M. W.: 778.98016

SYNONYMS

• IUPAC name: 1-[(R)-[(2R,4R,5S)-5-ethyl-1-azabicyclo[2.2.2]octan-2-yl](6-methoxyquinolin-4-yl)methoxy]-4-[(R)-[(2R,4S,5R)-5-ethyl-1-azabicyclo[2.2.2]octan-2-yl](6-methoxyquinolin-4-yl)methoxy]phthalazine
• IUPAC Traditional name: 1-[(R)-[(2R,4R,5S)-5-ethyl-1-azabicyclo[2.2.2]octan-2-yl](6-methoxyquinolin-4-yl)methoxy]-4-[(R)-[(2R,4S,5R)-5-ethyl-1-azabicyclo[2.2.2]octan-2-yl](6-methoxyquinolin-4-yl)methoxy]phthalazine
• Synonyms: AD-mix-alpha

DATABASE IDS

• MDL Number: MFCD00191975

PROPERTIES

• GHS Signal Word: Warning
• GHS Hazard statements: H315-H319-H335
• European Hazard Symbols: Harmful (Xn)
• GHS Precautionary statements: P261-P305 + P351 + P338
• Risk Statements: 22-32-36/37/38
• Safety Statements: 26
• Supplemental Hazard Statements: Contact with acids liberates very toxic gas.
• German water hazard class: 2

DETAILS

Description (English)

Components
Mixture contains: (DHQ)2PHAL (Cat. No. 392723) 0.0016 molePotassium carbonate, powder 0.4988 molePotassium ferricyanide 0.4988 molePotassium osmate dihydrate 0.0007 mole
Application
Catalyst employed in the Sharpless Asymmetric Dihyroxylation of (E,E)- or (E,Z)-1,3-dienoates.1 Also used in the preparation of β-hydroxy-γ-lactones from β,γ-unsaturated esters.2
Reagent for Sharpless Asymmetric Dihydroxylation.
General description
Contains chiral ligand (DHQ)2PHAL
Packaging
10, 50 g in glass bottle

Description (简体中文)

Components
混合物含有： (DHQ)2PHAL（产品号392723）0.0016 摩尔 碳酸钾粉末 0.4988 摩尔 铁氰化钾 0.4988 摩尔 二水合锇酸钾 0.0007 摩尔
Application
用于 (E,E)- 或 (E,Z)-1,3-二烯酸甲酯的 Sharpless 不对称双羟基化反应的催化剂。1也可用于由 β,γ-不饱酯制备 β-羟基-γ-内酯。2
用于 Sharpless 不对称双羟基化反应的试剂。
General description
含有手性配体 (DHQ)2PHAL
包装
10, 50 g in glass bottle