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Bis(pinacolato)diboron

Catalog No. 473294 Name Sigma Aldrich
CAS Number 73183-34-3 Website http://www.sigmaaldrich.com
M. F. C12H24B2O4 Telephone 1-800-521-8956
M. W. 253.93856 Fax
Purity 99% Email
Storage Chembase ID: 8893

SYNONYMS

Title
双联频哪醇硼酸酯
IUPAC name
4,4,5,5-tetramethyl-2-(tetramethyl-1,3,2-dioxaborolan-2-yl)-1,3,2-dioxaborolane
IUPAC Traditional name
bis(pinacolato)diboron
Synonyms
双戊酰二硼
4,4,4′,4′,5,5,5′,5′-Octamethyl-2,2′-bi-1,3,2-dioxaborolane

DATABASE IDS

CAS Number 73183-34-3
PubChem SID 24870893
MDL Number MFCD00799570

PROPERTIES

Empirical Formula (Hill Notation) C12H24B2O4
Purity 99%
Melting Point 137-140 °C(lit.)
MSDS Link Download
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
German water hazard class 3

DETAILS

Description (English)
Application
Reagent used for the cis-vicinal diborylation of acetylenes and olefins with Pt catalysis; borylation of aromatics by Pd catalysis.1
Substrate used in a new palladium-catalyzed cyclization of 1,6-enynes leading to homoallylic alkylboronates.
Used to construct a tetramethylpyrrolidine nitroxide scaffold for the synthesis of paramagnetic heterocycles by Suzuki coupling.
Packaging
1, 5, 25 g in glass bottle
100 g in poly bottle
500 g in glass bottle
Description (简体中文)
Application
用于构造四甲基吡咯烷硝基氧支架,以通过 Suzuki 偶联反应合成顺磁性杂环化合物。
用于铂催化乙炔和烯烃顺式邻二硼化反应的试剂;也可用于钯催化芳香烃的硼化反应。1
钯催化 1,6-烯炔环化生成高烯丙基烷基硼酸酯的新型反应的底物。
包装
1, 5, 25 g in glass bottle
100 g in poly bottle
500 g in glass bottle

REFERENCES