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(S,S)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II)_Molecular_structure_CAS_188264-84-8)
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(S,S)-(+)-N,N′-Bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminocobalt(II)

Catalog No. 474606 Name Sigma Aldrich
CAS Number 188264-84-8 Website http://www.sigmaaldrich.com
M. F. C36H52CoN2O2 Telephone 1-800-521-8956
M. W. 603.74348 Fax
Purity Email
Storage Chembase ID: 148126

SYNONYMS

Title
(S,S)-(+)-N,N′-双(3,5-二-叔丁基亚水杨基)-1,2-环己二胺钴(II)
IUPAC name
(4S,9S)-14,16,22,24-tetra-tert-butyl-18,20-dioxa-3,10-diaza-19-cobaltatetracyclo[19.4.0.04,9.012,17]pentacosa-1(21),2,10,12,14,16,22,24-octaene
IUPAC Traditional name
(4S,9S)-14,16,22,24-tetra-tert-butyl-18,20-dioxa-3,10-diaza-19-cobaltatetracyclo[19.4.0.04,9.012,17]pentacosa-1(21),2,10,12,14,16,22,24-octaene

DATABASE IDS

CAS Number 188264-84-8
PubChem SID 24871025
MDL Number MFCD01631278

PROPERTIES

Linear Formula [[[(CH3)3C]2C6H2-2-(O-)CH=N]2C6H10]Co
Melting Point >350 °C(lit.)
GHS Pictograms GHS06
GHS Signal Word Danger
GHS Hazard statements H302-H311-H332
European Hazard Symbols Harmful Harmful (Xn)
MSDS Link Download
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
GHS Precautionary statements P280-P312
Risk Statements 20/21/22
Safety Statements 36/37
German water hazard class 3

DETAILS

Description (English)
Application
Catalyst for the hydrolytic kinetic resolution of terminal epoxides1 and the enantioselective ring opening of meso epoxides.2
Packaging
1, 5, 25 g in glass bottle
Legal Information
Sold under license from Shasun Chemicals and Drugs Limited.
Description (简体中文)
Application
用于末端环氧化物的水解动力学拆分1和内消旋环氧化物不对称开环的催化剂。2
包装
1, 5, 25 g in glass bottle
Legal Information
经 Shasun Chemicals and Drugs Limited 授权销售。

REFERENCES