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Ethoxyacetylene solution_Molecular_structure_CAS_927-80-0)
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Ethoxyacetylene solution

Catalog No. 271365 Name Sigma Aldrich
CAS Number 927-80-0 Website http://www.sigmaaldrich.com
M. F. C4H6O Telephone 1-800-521-8956
M. W. 70.08984 Fax
Purity Email
Storage Chembase ID: 89254

SYNONYMS

Title
乙氧基乙炔 溶液
IUPAC name
ethoxyethyne
IUPAC Traditional name
ethoxy-ethyne

DATABASE IDS

Beilstein Number 741882
PubChem SID 24856434
MDL Number MFCD00009247
CAS Number 927-80-0

PROPERTIES

Concentration ~40 wt. % in hexanes
Linear Formula C2H5OC≡CH
Density 0.732 g/mL at 25 °C
Refractive Index n20/D 1.378
GHS Pictograms GHS07
GHS Pictograms GHS08
GHS Pictograms GHS09
GHS Signal Word Danger
GHS Hazard statements H304-H315-H336-H361-H373-H411
European Hazard Symbols Harmful Harmful (Xn)
European Hazard Symbols Nature polluting Nature polluting (N)
MSDS Link Download
GHS Precautionary statements P261-P273-P281-P301 + P310-P331
RID/ADR UN 1993 3/PG 2
Risk Statements 38-48/20-51/53-62-65-67
Safety Statements 36/37-61-62
Storage Temperature 2-8°C
Hazard Class 3
UN Number 1993
Packing Group 2
German water hazard class 3

DETAILS

Description (English)
Application
Used with N-vinylamides and triflic anhydride in a direct, three-component synthesis of pyridines.1 Also used to prepare α,β-unsaturated esters from ketones via a Meyer-Schuster rearrangement.2
Packaging
1, 5 g in glass bottle
Description (简体中文)
Application
与 N-乙烯基酰胺和三氟甲磺酸酐直接合成吡啶。1也用于通过 Meyer-Schuster 重排从酮制备 α,β-不饱和酯。2
包装
1, 5 g in glass bottle

REFERENCES