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Diethyl (methylthiomethyl)phosphonate_Molecular_structure_CAS_28460-01-7)
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Diethyl (methylthiomethyl)phosphonate

Catalog No. 366668 Name Sigma Aldrich
CAS Number 28460-01-7 Website http://www.sigmaaldrich.com
M. F. C6H15O3PS Telephone 1-800-521-8956
M. W. 198.220261 Fax
Purity 96% Email
Storage Chembase ID: 74937

SYNONYMS

Title
甲硫甲基膦酸二乙酯
IUPAC name
diethyl [(methylsulfanyl)methyl]phosphonate
IUPAC Traditional name
diethyl (methylsulfanyl)methylphosphonate
Synonyms
[(Methylthio)methyl]phosphonic acid diethyl ester

DATABASE IDS

CAS Number 28460-01-7
MDL Number MFCD00015131
PubChem SID 24862686

PROPERTIES

Linear Formula CH3SCH2P(O)(OC2H5)2
Purity 96%
Boiling Point 119-120 °C/10 mmHg(lit.)
Density 1.13 g/mL at 25 °C(lit.)
Flash Point 102 °C
Flash Point 215.6 °F
Refractive Index n20/D 1.465(lit.)
GHS Pictograms GHS07
GHS Signal Word Warning
GHS Hazard statements H315-H319-H335
European Hazard Symbols Irritant Irritant (Xi)
MSDS Link Download
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
GHS Precautionary statements P261-P305 + P351 + P338
Risk Statements 36/37/38
Safety Statements 26-37/39
German water hazard class 3

DETAILS

Description (English)
Packaging
25 g in glass bottle
Application
Reactant for:
• Synthesis of (+)-minfiensine via organocatalytic Diels-Alder/amine cyclization and 6-exo-dig radical cyclization1
• Preparation of fused nitrogen, sulfur, and phosphorus containing-heterocycles and relevant difurylpyridazine phosphonates with antimicrobial activity2
• Preparation of phosphorus and sulfur stereoisomers of Et menthyl [(methylsulfinyl)methyl]phosphonate3
Description (简体中文)
包装
25 g in glass bottle
Application
Reactant for:
• Synthesis of (+)-minfiensine via organocatalytic Diels-Alder/amine cyclization and 6-exo-dig radical cyclization1
• Preparation of fused nitrogen, sulfur, and phosphorus containing-heterocycles and relevant difurylpyridazine phosphonates with antimicrobial activity2
• Preparation of phosphorus and sulfur stereoisomers of Et menthyl [(methylsulfinyl)methyl]phosphonate3

REFERENCES