Allyltributylstannane

• Catalog No.: 271411
• CAS Number: 24850-33-7
• M. F.: C15H32Sn
• M. W.: 331.11558
• Purity: 97%

SYNONYMS

• Title: 烯丙基三丁基锡
• IUPAC name: tributyl(prop-2-en-1-yl)stannane
• IUPAC Traditional name: tributyl(prop-2-en-1-yl)stannane
• Synonyms: Allyltri-n-butyltin; Tributyl-2-propenylstannane; Allyltributyltin

DATABASE IDS

• EC Number: 246-494-3
• CAS Number: 24850-33-7
• Beilstein Number: 3588340
• PubChem SID: 24856436
• MDL Number: MFCD00010346

PROPERTIES

• Linear Formula: CH2=CHCH2Sn(CH2CH2CH2CH3)3
• Purity: 97%
• Boiling Point: 88-92 °C/0.2 mmHg(lit.)
• Density: 1.068 g/mL at 25 °C(lit.)
• Flash Point: 103 °C
• Flash Point: 217.4 °F
• Refractive Index: n20/D 1.486(lit.)
• GHS Signal Word: Danger
• GHS Hazard statements: H301-H312-H315-H319-H372-H410
• European Hazard Symbols: Toxic (T)
• European Hazard Symbols: Nature polluting (N)
• Personal Protective Equipment: Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
• GHS Precautionary statements: P273-P280-P301 + P310-P305 + P351 + P338-P314-P501
• RID/ADR: UN 2788 6.1/PG 3
• Risk Statements: 21-25-36/38-48/23/25-50/53
• Safety Statements: 36/37/39-45-60-61
• Hazard Class: 6.1
• UN Number: 2788
• Packing Group: 3
• German water hazard class: 3

DETAILS

Description (English)

Packaging
5, 25, 100 g in glass bottle
Application
Allylation reagent for aldehydes catalyzed by chiral Lewis acids1,2 and ytterbium(III) trifluoromethanesulfonate (cat. no. 430595).3 Undergoes tetrakis(triphenylphosphine)palladium(0) (cat. no. 216666) catalyzed coupling with iodoquinones4 and allyl acetates.5,6Efficient allylation of aldehydes leading to homoallylic alcohols with trichloro-1,3,5-triazene.7

Description (简体中文)

包装
5, 25, 100 g in glass bottle
Application
醛的烯丙基化试剂，该反应的催化剂为手性路易斯酸1,2和三氟甲烷磺酸镱(III)（产品号430595）。3在四(三苯基膦)钯(0)（产品号216666）催化下，与碘醌4和乙酸烯丙酯发生偶联反应。5,6 7用于醛与三氯-1,3,5-三氮烯的高效烯丙基化反应，生成高烯丙醇。