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Boron trifluoride tetrahydrofuran complex_Molecular_structure_CAS_462-34-0)
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Boron trifluoride tetrahydrofuran complex

Catalog No. 434280 Name Sigma Aldrich
CAS Number 462-34-0 Website http://www.sigmaaldrich.com
M. F. C4H8BF3O Telephone 1-800-521-8956
M. W. 139.9119296 Fax
Purity Email
Storage Chembase ID: 147981

SYNONYMS

Title
三氟化硼四氢呋喃络合物
IUPAC name
trifluoro(oxolan-1-ium-1-yl)boranuide
IUPAC Traditional name
trifluoro(oxolan-1-ium-1-yl)boranuide

DATABASE IDS

PubChem SID 24867185
MDL Number MFCD00040372
EC Number 207-325-9
CAS Number 462-34-0

PROPERTIES

Contains >0.5% sulfur dioxide as peroxide formation suppressor
Linear Formula BF3 · THF
Boiling Point 180 °C(lit.)
Density 1.268 g/mL at 25 °C(lit.)
Flash Point 92 °C
Flash Point 197.6 °F
Melting Point 11-13 °C(lit.)
GHS Pictograms GHS05
GHS Signal Word Danger
GHS Hazard statements H314
European Hazard Symbols Corrosive Corrosive (C)
MSDS Link Download
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
GHS Precautionary statements P280-P305 + P351 + P338-P310
RID/ADR UN 3265 8/PG 2
Risk Statements 34
Safety Statements 26-27-36/37/39-45
Hazard Class 8
UN Number 3265
Packing Group 2
German water hazard class 1

DETAILS

Description (English)
Application
Used extensively as a polymerization initiator.7,8
Reactant or reagent involved in:
• Deoxofluorination of alcohols and carbonyls1
• Synthesis of methacrylate-PEG-methacrylate-boron trifluoride self-doped gel polymer electrolytes2
• Hydroboration-oxidation of divinylferrocene3Reagent involved in the synthesis of biologically active molecules such as:
• NK1 receptor antagonists4
• Complex polyketide natural products5
• Selective serotonin reuptake inhibitors6
Packaging
100, 500 mL in glass bottle
Description (简体中文)
Application
广泛地用作聚合引发剂。7,8
Reactant or reagent involved in:
• Deoxofluorination of alcohols and carbonyls1
• Synthesis of methacrylate-PEG-methacrylate-boron trifluoride self-doped gel polymer electrolytes2
• Hydroboration-oxidation of divinylferrocene3Reagent involved in the synthesis of biologically active molecules such as:
• NK1 receptor antagonists4
• Complex polyketide natural products5
• Selective serotonin reuptake inhibitors6
包装
100, 500 mL in glass bottle

REFERENCES