Triruthenium dodecacarbonyl

• Catalog No.: 245011
• CAS Number: 15243-33-1
• M. F.: C12O12Ru3
• M. W.: 639.3312
• Purity: 99%

SYNONYMS

• Title: 十二羰基三钌
• IUPAC name: dodecakis(methanidylidyneoxidanium) triruthenium
• IUPAC Traditional name: dodecakis(carbon monoxide) triruthenium
• Synonyms: tri-Ruthenium dodecacarbonyl; 十二羰基合钌; Ruthenium carbonyl; 羰基钌

DATABASE IDS

• EC Number: 239-287-4
• CAS Number: 15243-33-1
• MDL Number: MFCD00011209
• PubChem SID: 24854727

PROPERTIES

• Linear Formula: Ru3(CO)12
• Purity: 99%
• GHS Signal Word: Warning
• GHS Hazard statements: H332
• European Hazard Symbols: Harmful (Xn)
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
• Risk Statements: 20
• German water hazard class: 3

DETAILS

Description (English)

Application
Carbonyl cluster precursor and H-transfer catalyst.1,2 Used in the reductive carbonylation of aromatic nitro compounds to carbamates.2 The phosphine-stabilized carbonyl cluster has been tethered to oxide supports.3 Applied in improved catalysis of the allylic amination of unactivated olefins by nitroarenes.4,5
Catalyst used in a [3+2+1] carbonylative cycloaddition of silylacteylenes and α,β-unsaturated ketones providing good yields of α-pyrones.
General description
Atomic number of base material: 44 Ruthenium
Packaging
1, 5 g in glass bottle

Description (简体中文)

Application
作为催化剂用于硅基乙炔类化合物与 α,β-不饱和酮的 [3+2+1] 羰基环加成反应，以高收率得到 α-吡喃酮。
羰基簇合物的前体和氢转移催化剂。1,2用于芳族硝基化合物的还原羰基化反应生成氨基甲酸酯。2已将膦稳定的羰基簇合物连到氧化物载体上。3在通过芳硝基化合物进行的未活化烯烃的烯丙基胺化反应中用于获得改进的催化效果。4,5
General description
Atomic number of base material: 44 Ruthenium
包装
1, 5 g in glass bottle