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(+)-(S)-N,N-Dimethyl-1-[(R)-1′,2-bis(diphenylphosphino)ferrocenyl]ethylamine_Molecular_structure_CAS_55650-59-4)
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(+)-(S)-N,N-Dimethyl-1-[(R)-1′,2-bis(diphenylphosphino)ferrocenyl]ethylamine

Catalog No. 344079 Name Sigma Aldrich
CAS Number 55650-59-4 Website http://www.sigmaaldrich.com
M. F. C38H37FeNP2 Telephone 1-800-521-8956
M. W. 625.499602 Fax
Purity 95% Email
Storage Chembase ID: 147944

SYNONYMS

Title
(+)-(S)-N,N-二甲基-1-[(R)-1′,2-双(二苯基膦基)二茂铁基]乙胺
IUPAC name
λ2-iron(2+) ion 3-(diphenylphosphanyl)cyclopenta-2,4-dien-1-ide 3-[(1S)-1-(dimethylamino)ethyl]-4-(diphenylphosphanyl)cyclopenta-2,4-dien-1-ide
IUPAC Traditional name
λ2-iron(2+) ion 3-(diphenylphosphanyl)cyclopenta-2,4-dien-1-ide 3-[(1S)-1-(dimethylamino)ethyl]-4-(diphenylphosphanyl)cyclopenta-2,4-dien-1-ide

DATABASE IDS

MDL Number MFCD00075283
PubChem SID 24861222
CAS Number 55650-59-4

PROPERTIES

Empirical Formula (Hill Notation) C38H37FeNP2
Purity 95%
Melting Point 138-142 °C(lit.)
Optical Rotation [α]20/D +350°, c = 0.5 in chloroform
GHS Pictograms GHS07
GHS Signal Word Warning
GHS Hazard statements H302-H312-H315-H319-H332-H335
European Hazard Symbols Harmful Harmful (Xn)
MSDS Link Download
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
GHS Precautionary statements P261-P280-P305 + P351 + P338
Risk Statements 20/21/22-36/37/38
Safety Statements 26-36
German water hazard class 3

DETAILS

Description (English)
Application
Ligand used in the asymmetric hydrogenation of (Z)-α-amido-cinnamic acids
Packaging
25, 100 mg in glass bottle
Description (简体中文)
Application
用于 (Z)-α-胺基-肉桂酸的不对称氢化反应的配体
包装
25, 100 mg in glass bottle

REFERENCES