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9-Borabicyclo[3.3.1]nonane solution_Molecular_structure_CAS_280-64-8)
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9-Borabicyclo[3.3.1]nonane solution

Catalog No. 459496 Name Sigma Aldrich
CAS Number 280-64-8 Website http://www.sigmaaldrich.com
M. F. C8H15B Telephone 1-800-521-8956
M. W. 122.0157 Fax
Purity Email
Storage Chembase ID: 140672

SYNONYMS

Title
9-硼双环[3.3.1]壬烷 溶液
IUPAC name
(1s,5s)-9-borabicyclo[3.3.1]nonane
IUPAC Traditional name
(1s,5s)-9-borabicyclo[3.3.1]nonane
Synonyms
9-BBN

DATABASE IDS

CAS Number 280-64-8
PubChem SID 24869563
Beilstein Number 605509
MDL Number MFCD00074742

PROPERTIES

Concentration 0.4 M in hexanes
Empirical Formula (Hill Notation) C8H15B
Boiling Point 68-70 °C
Density 0.691 g/mL at 25 °C
GHS Pictograms GHS02
GHS Pictograms GHS07
GHS Pictograms GHS08
GHS Pictograms GHS09
GHS Signal Word Danger
GHS Hazard statements H260-H304-H315-H336-H361f-H373-H411
European Hazard Symbols Flammable Flammable (F)
European Hazard Symbols Harmful Harmful (Xn)
European Hazard Symbols Nature polluting Nature polluting (N)
MSDS Link Download
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
GHS Precautionary statements P223-P231 + P232-P261-P273-P370 + P378-P422
RID/ADR UN 3399 4.3/PG 1
Risk Statements 14/15-38-48/20-51/53-62-65-67
Safety Statements 36/37-61-62
Hazard Class 4.3
UN Number 3399
Packing Group 1
German water hazard class 3

DETAILS

Description (English)
Packaging
1 L in Sure/Seal™
100 mL in Sure/Seal™
Application
Protecting group for alkenes†Reactant for:
• Linear SPPS synthesis of ubiquitin derivatives1
• Copper-catalyzed cross-coupling reactions of organoboron compounds with primary alkyl halides and pseudohalides2
• Intramolecular insertion of alkenes into palladium-nitrogen bonds3
• Preparation of (phosphonoacetyl)ornithine to study effect on arginine biosynthetic genes in yeast4
• Hetero-Diels-Alder reaction for synthesis of spirocyclic alkaloids5
Description (简体中文)
包装
1 L in Sure/Seal™
100 mL in Sure/Seal™
Application
Protecting group for alkenes†Reactant for:
• Linear SPPS synthesis of ubiquitin derivatives1
• Copper-catalyzed cross-coupling reactions of organoboron compounds with primary alkyl halides and pseudohalides2
• Intramolecular insertion of alkenes into palladium-nitrogen bonds3
• Preparation of (phosphonoacetyl)ornithine to study effect on arginine biosynthetic genes in yeast4
• Hetero-Diels-Alder reaction for synthesis of spirocyclic alkaloids5

REFERENCES