9-Borabicyclo[3.3.1]nonane solution

• Catalog No.: 459496
• CAS Number: 280-64-8
• M. F.: C8H15B
• M. W.: 122.0157

SYNONYMS

• Title: 9-硼双环[3.3.1]壬烷 溶液
• IUPAC name: (1s,5s)-9-borabicyclo[3.3.1]nonane
• IUPAC Traditional name: (1s,5s)-9-borabicyclo[3.3.1]nonane
• Synonyms: 9-BBN

DATABASE IDS

• CAS Number: 280-64-8
• PubChem SID: 24869563
• Beilstein Number: 605509
• MDL Number: MFCD00074742

PROPERTIES

• Concentration: 0.4 M in hexanes
• Empirical Formula (Hill Notation): C8H15B
• Boiling Point: 68-70 °C
• Density: 0.691 g/mL at 25 °C
• GHS Signal Word: Danger
• GHS Hazard statements: H260-H304-H315-H336-H361f-H373-H411
• European Hazard Symbols: Flammable (F)
• European Hazard Symbols: Harmful (Xn)
• European Hazard Symbols: Nature polluting (N)
• Personal Protective Equipment: Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
• GHS Precautionary statements: P223-P231 + P232-P261-P273-P370 + P378-P422
• RID/ADR: UN 3399 4.3/PG 1
• Risk Statements: 14/15-38-48/20-51/53-62-65-67
• Safety Statements: 36/37-61-62
• Hazard Class: 4.3
• UN Number: 3399
• Packing Group: 1
• German water hazard class: 3

DETAILS

Description (English)

Packaging
1 L in Sure/Seal™
100 mL in Sure/Seal™
Application
Protecting group for alkenes†Reactant for:
• Linear SPPS synthesis of ubiquitin derivatives1
• Copper-catalyzed cross-coupling reactions of organoboron compounds with primary alkyl halides and pseudohalides2
• Intramolecular insertion of alkenes into palladium-nitrogen bonds3
• Preparation of (phosphonoacetyl)ornithine to study effect on arginine biosynthetic genes in yeast4
• Hetero-Diels-Alder reaction for synthesis of spirocyclic alkaloids5

Description (简体中文)

包装
1 L in Sure/Seal™
100 mL in Sure/Seal™
Application
Protecting group for alkenes†Reactant for:
• Linear SPPS synthesis of ubiquitin derivatives1
• Copper-catalyzed cross-coupling reactions of organoboron compounds with primary alkyl halides and pseudohalides2
• Intramolecular insertion of alkenes into palladium-nitrogen bonds3
• Preparation of (phosphonoacetyl)ornithine to study effect on arginine biosynthetic genes in yeast4
• Hetero-Diels-Alder reaction for synthesis of spirocyclic alkaloids5