N-Phenyl-bis(trifluoromethanesulfonimide)

• Catalog No.: 295973
• CAS Number: 37595-74-7
• M. F.: C8H5F6NO4S2
• M. W.: 357.2500192
• Purity: 99%

SYNONYMS

• Title: N-苯基双(三氟甲烷磺酸亚胺)
• IUPAC name: 1,1,1-trifluoro-N-phenyl-N-trifluoromethanesulfonylmethanesulfonamide
• IUPAC Traditional name: 1,1,1-trifluoro-N-phenyl-N-trifluoromethanesulfonylmethanesulfonamide
• Synonyms: 1,1,1-Trifluoro-N-phenyl-N-[(trifluoromethyl)sulfonyl]methanesulfonamide; N-Phenyl-trifluoromethanesulfonimide; 1,1,1-三氟-N-苯基-N-[(三氟甲基)磺酰基]甲磺酰胺; NSC 240874; N,N-Bis(trifluoromethylsulfonyl)aniline; Phenyl triflimide; N,N-双(三氟甲磺酰基)苯胺; N-苯基-三氟甲磺酰亚胺; N-苯基双(三氟甲磺酰)亚胺

DATABASE IDS

• CAS Number: 37595-74-7
• MDL Number: MFCD00000404
• Beilstein Number: 1269141
• PubChem SID: 24857826

PROPERTIES

• Linear Formula: C6H5N(SO2CF3)2
• Purity: 99%
• Melting Point: 100-102 °C(lit.)
• GHS Signal Word: Warning
• GHS Hazard statements: H315-H319-H335
• European Hazard Symbols: Irritant (Xi)
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves
• GHS Precautionary statements: P261-P305 + P351 + P338
• Risk Statements: 36/37/38
• Safety Statements: 26-36
• German water hazard class: 3

DETAILS

Description (English)

Application
Mild triflating reagent.6,7,8
Used recently to convert a ketone to an enol triflate with KHMDS (324671) and thence an olefin with Pd(PPh3)4 (216666) and Bu3SnH (234788).
Acts as a transparent strong electron-withdrawing p-type dopant in carbon nanotubes1Reactant for: Synthesis of amphoteric alpha-boryl aldehydes2 Enantioselective synthesis of core ring skeleton of leucosceptroids A-D3 Stereoselective synthesis of monoamine reuptake inhibitor NS9544 acetate4 Stereoselective sulfoxidation5
Packaging
5, 25 g in glass bottle

Description (简体中文)

Application
温和的三氟甲磺酸化试剂。6,7,8
近来用于与 KHMDS (324671) 共同作用将酮转化为三氟甲磺酸烯醇酯，然后与 Pd(PPh3)4 (216666) 和 Bu3SnH (234788) 共同作用进一步转化为烯烃。
Acts as a transparent strong electron-withdrawing p-type dopant in carbon nanotubes1Reactant for: Synthesis of amphoteric alpha-boryl aldehydes2 Enantioselective synthesis of core ring skeleton of leucosceptroids A-D3 Stereoselective synthesis of monoamine reuptake inhibitor NS9544 acetate4 Stereoselective sulfoxidation5
包装
5, 25 g in glass bottle