(2-Bromoethoxy)-tert-butyldimethylsilane

• Catalog No.: 428426
• CAS Number: 86864-60-0
• M. F.: C8H19BrOSi
• M. W.: 239.22536
• Purity: 99%

SYNONYMS

• Title: (2-溴乙氧基)-叔丁基二甲基硅烷
• IUPAC name: (2-bromoethoxy)(tert-butyl)dimethylsilane
• IUPAC Traditional name: (2-bromoethoxy)(tert-butyl)dimethylsilane

DATABASE IDS

• MDL Number: MFCD00209550
• PubChem SID: 24866813
• CAS Number: 86864-60-0

PROPERTIES

• Contains: Na2CO3 as stabilizer
• Linear Formula: BrCH2CH2OSi(CH3)2C(CH3)3
• Purity: 99%
• Boiling Point: 70-75 °C/2.5 mmHg(lit.)
• Density: 1.115 g/mL at 25 °C(lit.)
• Flash Point: 73 °C
• Flash Point: 163 °F
• Refractive Index: n20/D 1.444(lit.)
• European Hazard Symbols: Irritant (Xi)
• Risk Statements: 36/37/38
• Safety Statements: 26-36
• German water hazard class: 3

DETAILS

Description (English)

Application
Reagent for N-protection with the TBSO-ethyl group. Treatment with Jones reagent effects hydrolysis and concomitant oxidation leading to N-acetic acids for further synthetic elaboration.
Useful reagent for the Pd-catalyzed N-hydroxyalkylation reactions1,2
Packaging
1, 10 g in glass bottle

Description (简体中文)

Application
用于 N-端 TBSO-乙基保护的试剂。用 Jones 试剂处理将发生水解并伴随着氧化反应生成N-乙酸，可进一步用于合成反应。
用于钯催化 N-羟烷基化反应的有效试剂1,2
包装
1, 10 g in glass bottle