(-)-(R)-N,N-Dimethyl-1-[(S)-1′,2-bis(diphenylphosphino)ferrocenyl]ethylamine

• Catalog No.: 344087
• CAS Number: 74311-56-1
• M. F.: C38H37FeNP2
• M. W.: 625.499602
• Purity: 95%

SYNONYMS

• Title: (-)-(R)-N,N-二甲基-1-[(S)-1′,2-双(二苯基膦基)二茂铁基]乙胺
• IUPAC name: λ^2-iron(2+) ion 3-(diphenylphosphanyl)cyclopenta-2,4-dien-1-ide 3-[(1R)-1-(dimethylamino)ethyl]-4-(diphenylphosphanyl)cyclopenta-2,4-dien-1-ide
• IUPAC Traditional name: λ^2-iron(2+) ion 3-(diphenylphosphanyl)cyclopenta-2,4-dien-1-ide 3-[(1R)-1-(dimethylamino)ethyl]-4-(diphenylphosphanyl)cyclopenta-2,4-dien-1-ide
• Synonyms: [R,R]-1-[1-二甲基氨乙基]-1′,2-双[二苯基膦]二茂铁; [R,R]-1-[1-Dimethylaminoethyl]-1′,2-bis[diphenylphosphino]ferrocene

DATABASE IDS

• CAS Number: 74311-56-1
• PubChem SID: 24861223
• MDL Number: MFCD00075284

PROPERTIES

• Empirical Formula (Hill Notation): C38H37FeNP2
• Purity: 95%
• Melting Point: 143-144 °C(lit.)
• Optical Rotation: [α]20/D -350°, c = 0.5 in chloroform
• GHS Signal Word: Warning
• GHS Hazard statements: H302-H312-H315-H319-H332-H335
• European Hazard Symbols: Harmful (Xn)
• Personal Protective Equipment: dust mask type N95 (US), Eyeshields, Gloves
• GHS Precautionary statements: P261-P280-P305 + P351 + P338
• Risk Statements: 20/21/22-36/37/38
• Safety Statements: 26-36
• German water hazard class: 3

DETAILS

Description (English)

Packaging
100 mg in glass bottle
Application
Ligand used in the enantioselective silylation of allylic chlorides.1

Description (简体中文)

包装
100 mg in glass bottle
Application
用于烯丙基氯的不对称硅烷化的配体。1