Iodotrimethylsilane

• Catalog No.: 195529
• CAS Number: 16029-98-4
• M. F.: C3H9ISi
• M. W.: 200.09353
• Purity: 97%

SYNONYMS

• Title: 三甲基碘硅烷
• IUPAC name: iodotrimethylsilane
• IUPAC Traditional name: trimethylsilyl iodide
• Synonyms: 碘代三甲硅烷; Trimethyliodosilane; TMIS

DATABASE IDS

• CAS Number: 16029-98-4
• PubChem SID: 24851696
• MDL Number: MFCD00001028
• EC Number: 240-171-0
• Beilstein Number: 1731136

PROPERTIES

• Contains: copper as stabilizer
• Linear Formula: (CH3)3SiI
• Purity: 97%
• Boiling Point: 106 °C(lit.)
• Density: 1.406 g/mL at 25 °C(lit.)
• Refractive Index: n20/D 1.471(lit.)
• GHS Signal Word: Danger
• GHS Hazard statements: H225-H314
• European Hazard Symbols: Flammable (F)
• European Hazard Symbols: Corrosive (C)
• Personal Protective Equipment: Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
• GHS Precautionary statements: P210-P280-P305 + P351 + P338-P310
• RID/ADR: UN 2924 3/PG 2
• Risk Statements: 11-14-34
• Safety Statements: 16-26-36/37/39-43-45
• Storage Temperature: -20°C
• Supplemental Hazard Statements: Reacts violently with water.
• Hazard Class: 3
• UN Number: 2924
• Packing Group: 2
• German water hazard class: 3

DETAILS

Description (English)

Application
Efficient reagent for cleaving ethers, esters, carbamates, ketals, and lactones.1
For the introduction of the TMS group, e.g., TMS enol ethers. Key reagent for the selective deprotection of an N-Cbz group in the presence of a trimethyltin moiety.
Reagent was recently reported to convert allyl- and benzylphosphotriesters to the corresponding iodides.
Packaging
5, 25, 100 g in ampule

Description (简体中文)

Application
最近报道用于将烯丙基以及苄基磷酸三酯转化为相应的碘化物的试剂。
用于引入 TMS 基团，如 TMS 烯醇醚。用于在三甲基锡基存在的条件下对 N-Cbz 基团进行选择性脱保护的重要试剂。
用于裂解醚、酯、氨基甲酸盐、缩酮和内酯的有效试剂。1
包装
5, 25, 100 g in ampule