Trimethylaluminum solution

• Catalog No.: 198048
• CAS Number: 75-24-1
• M. F.: C3H9Al
• M. W.: 72.085098

SYNONYMS

• Title: 三甲基铝 溶液
• IUPAC name: trimethylalumane
• IUPAC Traditional name: trimethylaluminium

DATABASE IDS

• MDL Number: MFCD00008252
• PubChem SID: 24851857
• Beilstein Number: 3587197
• CAS Number: 75-24-1

PROPERTIES

• Concentration: 2.0 M in toluene
• Linear Formula: (CH3)3Al
• Density: 0.81 g/mL at 25 °C
• Flash Point: 4 °C
• Flash Point: 39.2 °F
• GHS Signal Word: Danger
• GHS Hazard statements: H225-H250-H260-H304-H314-H336-H361d-H373
• European Hazard Symbols: Flammable (F)
• European Hazard Symbols: Corrosive (C)
• Personal Protective Equipment: Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
• GHS Precautionary statements: P210-P222-P223-P231 + P232-P370 + P378-P422
• RID/ADR: UN 3399 4.3/PG 1
• Risk Statements: 63-11-14-17-34-48/20-65-67
• Safety Statements: 16-26-36/37/39-45-62
• Supplemental Hazard Statements: Reacts violently with water.
• Hazard Class: 4.3
• UN Number: 3399
• Packing Group: 1
• German water hazard class: 2

DETAILS

Description (English)

Application
Used in a recently reported Al-catalyzed oxidation based on Oppenauer chemistry providing excellent yields of aldehydes and ketones.1 As a (1:1) complex with binol catalyzes the dynamic kinetic resolution of secondary alcohols with Novozym 435.2
Packaging
1 L in Sure/Seal™
View returnable container options.
4×25, 100, 800 mL in Sure/Seal™
8, 18 L in Kilo-Lab™

Description (简体中文)

Application
用于最近报道的基于 Oppenauer 化学的铝催化氧化反应，可得到高收率的醛和酮。1与联萘酚形成 1:1 的络合物，可催化 Novozym 435 作用下仲醇的动态动力学拆分。2
包装
1 L in Sure/Seal™
View returnable container options.
4×25, 100, 800 mL in Sure/Seal™
8, 18 L in Kilo-Lab™