Tetrapropylammonium perruthenate

• Catalog No.: 330744
• CAS Number: 114615-82-6
• M. F.: C12H28NO4Ru
• M. W.: 351.42502
• Purity: 97%

SYNONYMS

• Title: 四丙基高钌酸铵
• IUPAC name: tetrapropylazanium rutheniumoylolate
• IUPAC Traditional name: tetrapropylammonium rutheniumoylolate
• Synonyms: TPAP

DATABASE IDS

• CAS Number: 114615-82-6
• MDL Number: MFCD00074914
• PubChem SID: 24859883

PROPERTIES

• GHS Precautionary statements: P220-P261-P305 + P351 + P338
• RID/ADR: UN 1479 5.1/PG 2
• Risk Statements: 5-8-36/37/38
• Safety Statements: 17-26-36
• Hazard Class: 5.1
• UN Number: 1479
• Packing Group: 2
• German water hazard class: 3
• GHS Signal Word: Danger
• GHS Hazard statements: H272-H315-H319-H335
• European Hazard Symbols: Oxidising (O)
• European Hazard Symbols: Irritant (Xi)
• Personal Protective Equipment: Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
• Linear Formula: (CH3CH2CH2)4NRuO4
• Purity: 97%
• Melting Point: ~160 °C (dec.)(lit.)

DETAILS

Description (English)

Application
A soluble, nonvolatile, air-stable, mild oxidant which can be used either stoichiometrically or catalytically with a suitable co-oxidant.
Oxidant used to convert N,N′-dihydroxyimidazolidines to nitronyl nitroxide free radicals.1 Oxidation of hydroxyl-substituted tri-n-butylammonium trifluoroborates to aldehydes and ketones without concomitant cleavage of the carbon-boron bond.2,3
Packaging
1 g in glass bottle
250 mg in glass bottle

Description (简体中文)

Application
可溶、非挥发性、空气稳定的温和催化剂，可与适当的共氧化剂按化学计量或作为催化用途使用。
氧化剂，用于将 N,N′-二羟基咪唑啉转化为氮氧自由基。1将羟基取代的三-正丁基铵三氟硼酸盐氧化成醛和酮，而不会伴随碳-硼键的断裂。2,3
包装
1 g in glass bottle
250 mg in glass bottle