N-(Methoxymethyl)-N-(trimethylsilylmethyl)benzylamine

• Catalog No.: 420697
• CAS Number: 93102-05-7
• M. F.: C13H23NOSi
• M. W.: 237.41332
• Purity: 96%

SYNONYMS

• Title: N-(甲氧基甲基)-N-(三甲基硅烷基甲基)苄胺
• IUPAC name: benzyl(methoxymethyl)[(trimethylsilyl)methyl]amine
• IUPAC Traditional name: benzyl(methoxymethyl)[(trimethylsilyl)methyl]amine

DATABASE IDS

• MDL Number: MFCD00674005
• CAS Number: 93102-05-7
• PubChem SID: 24866346

PROPERTIES

• Linear Formula: C6H5CH2N(CH2OCH3)CH2Si(CH3)3
• Purity: 96%
• Boiling Point: 76 °C/0.3 mmHg(lit.)
• Density: 0.928 g/mL at 25 °C(lit.)
• Flash Point: 66 °C
• Flash Point: 150.8 °F
• Refractive Index: n20/D 1.492(lit.)
• GHS Signal Word: Warning
• GHS Hazard statements: H315-H319-H335
• European Hazard Symbols: Irritant (Xi)
• Personal Protective Equipment: Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
• GHS Precautionary statements: P261-P305 + P351 + P338
• Risk Statements: 36/37/38
• Safety Statements: 26
• German water hazard class: 3

DETAILS

Description (English)

Application
Forms azomethine ylides which readily undergo [3+2] cycloaddition to α,β-unsaturated esters affording N-benzyl substituted pyrrolidines in good yields.1
Reacted in asymmetric 1,3-dipolar cycloadditions in the practical, large-scale synthesis of chiral pyrrolidines.
Packaging
1, 5, 25, 100 g in glass bottle

Description (简体中文)

Application
形成偶氮甲碱叶立德，易于进行 [3+2] 环加成反应，生成能够提供高产率 N-苄基取代吡咯烷的 α,β-不饱和酯。1
用于在实际大量合成手性吡咯烷中进行不对称 1,3-偶极环加成反应。
包装
1, 5, 25, 100 g in glass bottle