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Chlorotris(trimethylsilyl)silane

Catalog No. 409405 Name Sigma Aldrich
CAS Number 5565-32-2 Website http://www.sigmaaldrich.com
M. F. C9H27ClSi4 Telephone 1-800-521-8956
M. W. 283.10568 Fax
Purity 97% Email
Storage Chembase ID: 143066

SYNONYMS

Title
氯三(三甲基甲硅烷基)硅烷
IUPAC name
2-chloro-1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)trisilane
IUPAC Traditional name
2-chloro-1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)trisilane

DATABASE IDS

CAS Number 5565-32-2
MDL Number MFCD01321222
PubChem SID 24865643

PROPERTIES

Linear Formula [(CH3)3Si]3SiCl
Purity 97%
Flash Point 31 °C
Flash Point 87.8 °F
Melting Point 50-52 °C(lit.)
GHS Pictograms GHS02
GHS Pictograms GHS07
GHS Signal Word Danger
GHS Hazard statements H228-H261-H315-H319-H335
European Hazard Symbols Flammable Flammable (F)
European Hazard Symbols Irritant Irritant (Xi)
MSDS Link Download
Personal Protective Equipment Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
GHS Precautionary statements P210-P231 + P232-P261-P305 + P351 + P338-P422
RID/ADR UN 3132 4.3
Risk Statements 11-29-36/37/38
Safety Statements 7/8-16-26-36/37-43-MissingPhraseText-N15.00511280
Supplemental Hazard Statements Contact with water liberates toxic gas.
Hazard Class 4.3
UN Number 3132
German water hazard class 3

DETAILS

Description (English)
Packaging
10, 25 g in poly bottle
Application
Super Silyl Protecting GroupsUsed for:
• Insertion into a P-P bond1
• Diastereoselective aldol and cascade reactions2
• Preparation of hypersilyl substituted monophosphines and diphosphines3
Description (简体中文)
包装
10, 25 g in poly bottle
Application
Super Silyl Protecting GroupsUsed for:
• Insertion into a P-P bond1
• Diastereoselective aldol and cascade reactions2
• Preparation of hypersilyl substituted monophosphines and diphosphines3

REFERENCES